Elastomers and rubber shapes are natural or synthetic polymers that exhibit elastic properties and can be formed into finished or semi-finished stock. These amorphous polymers are usually thermosets, but are also available as thermoplastics. Elastic polymer (elastomer) and rubber shapes are available in different forms and sizes, and often use filler materials. The chemical system , filler material, and other characteristics of these products determine their thermal, mechanical, electrical and optical properties.
Thermoset Elastomers vs. Thermoplastic Elastomers (TPE)
Elastomers and rubber shapes may be divided into thermosets and thermoplastics.
- Thermosetting elastomers are subjected to heat and pressure (vulcanization) to impart strength. This process causes permanent crosslinking and imparts high elastic properties. Cured thermosets generally have higher resistance to heat than thermoplastics, but cannot be reprocessed through melting. Often, thermoset elastomers are used in fluid sealing applications.
- Thermoplastic elastomers (TPE) are processed through blow, extrusion, or injection molding instead of vulcanization. These products are relatively expensive, but provide good chemical resistance and high heat resistance. Rubber elastomers, as they are also called, are classified into six groups: styrenic block copolymers, polyolefin blends, elastomeric alloys, thermoplastic polyurethanes, thermoplastic copolyesters and thermoplastic polyamides.
When selecting products, industrial buyers can limit their search to either thermoset or TPE products.
The GlobalSpec SpecSearch database also contains information about gel elastomers, highly viscoelastic polymer products that have excelled shock absorption and damping characteristics. Typically, they are produced via a two-part casting system. Subcategories include thermoplastic, polyurethane, and silicone gel elastomers. Applications range from medical devices to motorcycle seats to computer keyboard wrist wrests.
Chemical System and Filler Material
Industrial buyers need to specify the chemical system for elastomers and stock shapes, and can select products that use a filler material. There are six chemical systems, each of which provides characteristics suitable for specific applications.
- Fluoroelastomer products are used in applications that require superior chemical resistance or low friction.
- Polyethylene (PE) has good friction and mechanical properties.
- Polyurethane (PU) provides excellent flexibility, impact resistance, and durability.
- Silicone rubber has excellent resistance to temperature extremes and can be compounded with additives to impart electrical insulation properties. It has a low degree of water resistance, however.
- Acrylics can be compounded with ethylene to provide a high degree of oil, ozone, ultraviolet (UV), and weather resistance.
- Butyl rubber is used to make products that are air tight and gas impermeable.
In terms of filler materials, some elastomer and rubber shapes contain chopped, continuous, wound, or aramid fibers. Others contain glass or metal fillers, inorganic or reinforced compounds, or carbon or graphite powders. Unfilled products are also available.
Forms and Sizes
Elastomer and rubber shapes are available as bars, films, plates, profiles, rods and shims with square, spherical, angular, rectangular, hexagonal, tubular, I-shaped, and T-shaped c ross-sections. Size and dimensional criteria include overall thickness, overall width or outer diameter (OD), overall length, and inner diameter (ID).
Related Products & Services
Conductive compounds provide an electrically and/or thermally conductive path between components.
Conformal coatings encapsulate circuit boards and their electronic components in order to prevent the ingress of moisture, fungus, dust and other environmental contaminants.
Epoxy adhesives are chemical compounds for joining components. They require clean surfaces and are valued for their toughness and resistance to chemical and environmental damage.
Gel elastomers are highly viscoelastic polymer gel materials that have excellent shock absorption and damping characteristics. They are available in a variety of material types and grades.
Pressure Sensitive Adhesives (PSA) and Contact Adhesives
Pressure sensitive adhesives (PSA) and contact adhesives adhere to most surfaces with very slight pressure. They are available in solvent and latex or water-based forms.
Silicone Adhesives and Sealants
Silicone adhesives and sealants have a high degree of flexibility and a very high temperature resistance (up to 600° F), but lack the strength of other epoxy or acrylic resins.
Thermoplastics and Thermoplastic Materials
Thermoplastics and thermoplastic materials soften when heated and harden when cooled. They can withstand many heating and cooling cycles and are often suitable for recycling.