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The Pitfalls of Process TOC Analysis and How To Avoid Them
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The Pitfalls of Process TOC Analysis and How To Avoid Them
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From TOC Systems, Inc.
Since the introduction of Total Organic Carbon (TOC) Analyzers by Dow, Union Carbide and Automated Environmental Systems in the1960’s, they have proven to be an invaluable tool in the environmental and process monitoring fields. While technologies have advanced since then, certain performance characteristics required for true process control have been notably absent. The purpose of this paper is to discuss those limitations as evidenced by field experience, maintenance requirements and other practical considerations. Failure mode and effect analyses are summarized for critical components, as well as suggested corrective design, operation, and maintenance approaches, with a view toward minimizing cost of ownership.
Generally, all TOC Analyzers employ the same basic technique as depicted in figure 1. A liquid sample is initially introduced to an Inorganic Carbon (IC) removal stage, where acid is added to the sample, dropping its pH to approximately 2.0. At this point, the IC is converted to carbon dioxide (CO2) gas, which is stripped out of the liquid by a sparge carrier gas. The remaining inorganic carbon-free sample is then delivered to the Oxidation Chamber.
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Total organic carbon (TOC) analyzers measure the amount of total organic carbon present in a liquid sample.
Combustion analyzers and flue gas analyzers measure the gas content of emissions in order to monitor the combustion efficiency of fuel-burning equipment.
Calibration and repair services for vibration, acoustic, electrical / electronic test, environmental, dimensional, NDT, analytical, process and other specialty instruments, sensors and related equipment.
Laboratory and calibration gases are specialized for use as laboratory standards, as well as for detection, sample preparation, environmental monitoring and analysis applications.
Gas, liquid and solids samplers are used to take samples of media from process streams, reactors or storage vessels.
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