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Chemical vapor deposition (CVD) of hydrocarbons over a metal catalyst is a classical method that has been used to produce various carbon materials such as carbon fibers, filaments, etc. for over twenty years. Large amounts of CNTs can be formed by catalytic CVD of acetylene over Co and Fe catalysts supported on silica or zeolite. The carbon deposition activity seems to relate to the cobalt content of the catalyst, whereas the CNTs' selectivity seems to be a function of the pH in catalyst preparation. Fullerenes and bundles of SWNTs were also found among the MWNTs produced on the carbon/zeolite catalyst.
Producing CNTs via Catalyzed Chemical Vapor Deposition enables companies to produce CNTs in much larger volumes and subsequently sell them for lower prices.
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References (3.1) A. Moisala, A. G. Nasibulin and E. I. Kauppinen, The role of metal nanoparticles in the catalytic production of single-walled carbon nanotubes a review , J. Phys. Cond. Matter, 15,...
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Wenping Ma, Edwin L. Kugler, and Dady B. Dadyburjor Department of Chemical Engineering, West Virginia University, Morgantown, WV 26506-6102 1. Abstract The effects of Mo loading and type of...
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