Smithells Light Metals Handbook

Chapter 8: Metal Finishing

The processes and solutions described in this section are intended to give a general guide to surface finishing procedures. To operate these systems on an industrial scale would normally require recourse to one of the Chemical Supply Houses which retail properietary solutions.

8.1 Cleaning and Pickling Processes

Vapour Degreasing

Used to remove excess oil and grease. Components are suspended in a solvent vapour, such as tri-or tetrachloroethylene.

Note: Both vapours are toxic and care should be taken to ensure efficient condensation or extraction of vapours.

Emulsion Cleaning

An emulsion cleaner suitable for most metals can be prepared by diluting the mixture given below with a mixture of equal parts of white spirit and solvent naphtha.

Pine oil

62 g

Oleic acid

10.8 g

Triethanolamine

7.2 g

Ethylene glycol-monobutyl ether

20 g

This is used at room temperature and should be followed by thorough swilling.

TABLE 8.1: ALKALINE CLEANING SOLUTIONS

Metal to be cleaned

Composition of solution

Temperature

oz gal -1

gl -1

F

C

Remarks

All common metals other than aluminium and zinc, but including magnesium

Sodium hydroxide (NaOH)

6

37.5

180 200

80 90

For heavy duty

Sodium carbonate (Na 2CO 3)

4

25.0

Tribasic sodium phosphate (Na 3PO 4.12H 2O)

1

6.2

Wetting agent

1.5

Sodium hydroxide

2

12.5

180 200

80 90

For medium duty

Sodium carbonate

4

25.0

Tribasic sodium phosphate

2

12.5

Sodium metasilicate (Na 2SiO

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