Handbook of Flotation Reagents: Chemistry, Theory and Practice: Flotation of Sulfide Ores

Chapter 12: Flotation of Copper Sulfide Ores

12.1 COPPER ORES AND MINERALS

More than 170 copper-containing minerals are known and only 10-15 of these minerals have any economic value. The most important economic copper minerals are chalcopy-rite, chalcocite, bornite and covellite. Table 12.1 lists the copper minerals of economic value.

Table 12.1: Copper sulfide minerals with economic value

Mineral

Chemical formula

Copper content (%)

Specific gravity (g/cm 3)

Native copper

Cu

100.0

8.8

Bornite

Cu 5FeS 4

63.3

5.0

Chalcocite

Cu 2S

79.8

5.7

Chalcopyrite

CuFeS 2

34.6

4.2

Covellite

CuS

66.4

4.6

Digenite

Cu 2S

79.8

5.7

Enargite

Cu 3AsS 4

48.3

4.4

Tennatite

3Cu 2S As 2S 3

57.5

4.4

Tetrahedrite

3Cu 2S Sb 2S 3

52.1

4.8

From a processing point of view, copper ores could be divided into:

  • Copper sulfide ores, where the pyrite content can vary from 10% to 90%. The predominant sulfide mineral in this ore is pyrite, but may also contain pyrrhotite and mar-casite. Some copper sulfide ores also contain significant quantities of gold and silver. According to the mineral compositions, these ores can be sub-divided into three main groups including (a) copper-gold ore, (b) copper sulfide ore with moderate pyrite content and (c) massive sulfide copper ores.

  • Copper porphyry ores are the most abundant copper ores; more than 60% of the world's copper production is from these ores. They most often contain molybdenum, which is recovered as a by-product. There are several major areas in the world where copper mineralization occurs, known...

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