III-Nitride Semiconductor Materials

Haipeng Tang [1] and James B.Webb [2]
Although current commercial production of GaN based LEDs and LDs is dominated by the MOCVD technique, the emerging market demand for GaN electronics could see GaN-MBE technology becoming an important production tool for future generation RF and microwave electronic components. This chapter looks at the recent advances in molecular beam epitaxy of III-N materials for high-speed electronics applications. Two variations of the nitride MBE technique, ammonia-MBE and plasma-assisted MBE, are covered with reference to key growth challenges such as the growth of semi-insulating GaN. The advantages of the GaN MBE technology for producing high performance GaN/AlGaN HFETs such as the controlled carbon doping of semi-insulating GaN, high material purity and electron mobility, good uniformity and device scalability, and excellent small and large signal RF performance are reviewed.
Molecular Beam Epitaxy (MBE) has now reached a high level of sophistication in terms of ultra-high vacuum capability, material purity, in-situ monitoring and control. The technology of MBE has been developed over many decades and today the technique has been successfully applied to the growth of a broad range of materials, particularly group III-V semiconductor compounds. It is still a tool of choice for many researchers for developing new material systems due to its extensive "in-situ" monitoring capabilities. Many reviews are available describing the technique of MBE1 , 2 and thus this chapter will be limited to a discussion of the MBE technique as applied to group III-Nitride semiconductors for high electron mobility transistor(HEMT)...