Molecular to Global Photosynthesis

Appendix III: List of Symbols

Symbol

Preferred Unit

Description

a

absorptance (absorptivity)

A

electron acceptor

c i

mol dm ?3

molar concentration of species i

D

electron donor

D i

cm 2 s ?1

diffusion coefficient of species i

E ox,RD

V vs. ref.

electrode potential for the reaction Ox + ne ? ? Rd vs. reference electrode

E

V vs. ref.

standard electrode potential (based on activities)

E m

V vs. ref.

midpoint electrode potential

G

eV molecule ?1 or kJ mole ?1

Gibbs free energy

H

eV molecule ?1 or kJ mole ?1

enthalpy

j s ?

photons m ?2s ?1

spectral photon flux with respect to wavelength

q

C

unsigned charge on electron (1.602 10 ?19 C)

p

atm or Pa

pressure

T

K

absolute temperature

T

transmittance (transmissivity)

U

eV molecul ?1 or kJ mol ?1

internal energy

U g

eV molecul ?1 or kJ mol ?1

bandgap or threshold energy for reaction

V

m 3

volume

V

V

voltage

?

cm ?1 or m ?1

optical absorption coefficient

? ?

cm ?1 or m ?1

optical absorption coefficient at wavelength ?

? op

optical dielectric constant

? s

static dielectric constant

? PS

photosynthetic energy-storage efficiency

?

nm

wavelength

?

eV molecule ?1

reorganisation energy (of an electron-transfer reaction)

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