Water Technology: An Introduction for Environmental Scientists and Engineers, Second Edition

Chapter 20: Physico-Chemical Treatment Processes

INTRODUCTION

There are a wide range of non-biological unit processes, some of which are applicable to both water and wastewater treatment. Advanced processes are those not normally employed in conventional treatment but are required to conform to ever stricter water quality and discharge standards (Sections 8.1 and 8.3). Advanced water treatment processes include iron and manganese removal, softening, ion exchange, adsorption and chemical oxidation. Advanced (tertiary) wastewater treatment is more varied and includes biological processes for nitrification, denitrification and phosphorus removal (Section 18.4), as well as a range of physico-chemical processes (Table 20.1).

Table 20.1: Principal advanced physico-chemical wastewater treatment processes

Process

Removal function

Filtration

Suspended solids

Air stripping

Ammonia

Breakpoint chlorination

Ammonia

Ion exchange

Nitrate, dissolved inorganic solids

Chemical precipitation

Phosphorus, dissolved inorganic solids

Carbon adsorption

Toxic compounds, refractory organics

Chemical oxidation

Toxic compounds, refractory organics

Ultrafiltration

Dissolved inorganic solids

Reverse osmosis

Dissolved inorganic solids

Electrodialysis

Dissolved inorganic solids

Volatilization and gas stripping

Volatile organic compounds

20.1 EQUALIZATION

While sewage displays a diurnal variation in flow (Fig. 13.3), wastewater treatment plants are designed to handle normal variations of up to 3 times the dry weather flow (3DWF). The composition of the sewage entering large treatment plants also varies very little during this period. The exception is storm water which can result in an initial toxic shock loading as the stored contents of road-side gully pots are displaced...

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