Principles of Nanotechnology: Molecular-Based Study of Condensed Matter in Small Systems

The interactions between atoms and molecules are either of covalent or non-covalent type [1,2]. Covalent interactions are in a form of chemical bond in compounds that result from the sharing of one or more pairs of electrons. Atoms can combine by forming molecules to achieve an octet of valence electrons by sharing electrons. In this process, the electron clouds of every two atoms overlap where they are thicker and their electric charge is stronger. Since the nuclei of the two atoms have stronger attractive potentials to their respective thick electron clouds than their mutual repulsive potential (due to their far distance from one another), the two atoms are held together and form a molecule (see Figure 1).
As a result, the formation of covalent bonds requires overlapping of partially occupied orbitals of interacting atoms, which share a pair of electrons. On the other hand, in non-covalent interactions no overlapping is necessary because the attraction comes from the electrical properties of the interacting atoms and molecules. The electrons in the outermost shell are named the valence electrons, which are the electrons on an atom that can be gained or lost in a chemical reaction. The number of covalent bonds, which an atom can form, depends on how many valence electrons it has. Generally, covalent bond implies the sharing of just a single pair of electrons. The sharing of two pairs of electrons is...