Thermochromic Phenomena in Polymers

3.4: Comparison Between the Three Different Classes of Thermochromic Additives

3.4 Comparison Between the Three Different Classes of Thermochromic Additives

A comparison between the classes of thermochromic additives presented in Sections 3.1 3.3 is given in Table 3.2. The outstanding property of organic thermochromic materials is that switching temperature and colour can be customised. Moreover, the narrow absorption band allows the creation of multiple switching effects by a combined use of several thermochromic additives. With a view to application, these properties are very important. They enable a flexible adjustment of the thermochromic properties for specific application. The advantage of inorganic pigments is their thermostability above 200 C and their light stability which is even suitable for outdoor application. However, most of the inorganic pigments for these applications are toxic.

Table 3.2: Comparison between thermochromic inorganic pigments, organic thermochromic microcapsules and conjugated polymers

Material property

Inorganic pigments

Organic microcapsules

Conjugated polymers

Switching temperature

70 500 C

0 130 C

?

Thermostability

Stability at 500 C possible

<200 C

<200 C

Light stability

Suitable for outdoor applications

Insufficient

Insufficient

Multiswitching between different colours possible?

Reversible: no; only two colours

Irreversible: yes

Yes

No

Switching temperature adjustable?

Fixed transition temperatures

Switching temperature is adjustable

Fixed transition temperatures

Colour variable at constant switching temperature?

Fixed colours

Colour variable by changing dye component

Fixed colours

Toxicity

Toxic

Non-toxic

Non-toxic

UNLIMITED FREE
ACCESS
TO THE WORLD'S BEST IDEAS

SUBMIT
Already a GlobalSpec user? Log in.

This is embarrasing...

An error occurred while processing the form. Please try again in a few minutes.

Customize Your GlobalSpec Experience

Category: Pigments
Finish!
Privacy Policy

This is embarrasing...

An error occurred while processing the form. Please try again in a few minutes.