Developments and Applications in Solubility

Theory, Techniques and Results

Chapter List

Chapter 1: Thermodynamics of Nonelectrolyte Solubility
Chapter 2: Thermodynamics of Electrolyte Solubility
Chapter 3: Experimental, Calculated and Predicted Solubilities - Basis for the Synthesis and Design of Thermal Separation Processes
Chapter 4: Solubility of Gases in Ionic Liquids, Aqueous Solutions, and Mixed Solvents
Chapter 5: Solubility Phenomena in Green Quaternary Mixtures (Ionic liquid + Water + Alcohol + CO2)
Chapter 6: The Solubility of Gases in Water and Seawater
Chapter 7: Isotope Effects on Solubility
Chapter 8: Solubility of Organic Solids for Industry
Chapter 9: CO2 Solubility in Alkylimidazolium-Based Ionic Liquids

EMMERICH WILHELM
Institute of Physical Chemistry, University of Wien, W hringer Stra ?e 42, Wien (Vienna) A-1090, Austria

Magic means rather different things to different people.
Brigadier Donald Ffellowes in The Kings of the Sea , by S.E. Lanier, The Magazine of Fantasy & Science Fiction, November 1968.

1.1 Introduction

The liquid state is one of the three principal states of matter. The majority of chemical synthesis reactions are carried out in the liquid state, and separation processes usually involve liquid/fluid states, i.e. solutions. Thus, not surprisingly, for a century and a half experimental investigations of physical properties of solutions and of phase equilibria involving solutions (vapour liquid equilibrium: VLE; liquid liquid equilibrium: LLE; solid liquid equilibrium: SLE; solid vapour equilibrium: SVE) have held a prominent position in physical chemistry. The scientific insights gained in these studies can hardly be overrated, and have been of immense value for the development of the highly formalized, general discipline of...

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