Handbook of Plastics Joining: A Practical Guide, Second Edition

Chapter 26: Polyamide-imide

26.1 Adhesive Bonding

Solvay Advanced Polymers: Torlon

Torlon poly(amide-imide) parts can be joined with commercial adhesives, extending design options. A variety of adhesives including amide-imide, epoxy and cyanoacrylate can be used to bond Torlon parts. Cyanoacrylates have poor environmental resistance and are not recommended. Silicone, acrylic, and urethane adhesives are generally not recommended unless environment conditions preclude other options. The amide-imide adhesive is made by dissolving 35 parts of Torlon 4000T PAI powder in 65 parts of N-methylpyrrolidone (NMP). It should be noted that NMP is a flammable organic solvent and the appropriate handling procedures recommended by EPA, NIOSH and OSHA should be followed.

Torlon 4203L, 5030, and 7130 are relatively easy to bond. Bearing grades 4301, 4275, and 4435 have inherent lubricity, and are more difficult to bond. Table 26.1 compares the shear strengths of these grades bonded with epoxy, cyanoacrylate and amide-imide adhesives.

Table 26.1: Shear Strength of Torlon PAI to Torlon PAI Bonds

PAI grade

Epoxy [a]

Cyanoacrylate [b]

Amide-imide

psi

MPa

psi

MPa

psi

MPa

Torlon 4203L

6000+

41.4

2780

19.2

5000+

34.5

Torlon 4301

2250

15.5

1740

12.0

2890

19.9

Torlon 4275

3500

24.1

1680

11.6

3400

23.4

Torlon 5030

4780

33.0

3070

21.2

5140

35.4

Torlon 7130

6400 +

44.1

3980

27.4

4750

32.8

[a]Hysol EA 9330 from Dexter Corporation.

[b]CA 5000 from Lord Corporation.

Bonding surfaces should be free of contaminants, such as oil, hydraulic fluid, and dust. Torlon parts should be dried for at least 24 hours at 300 F...

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