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Supplier: Accuris
Description: Emergency procedure guide - Transport - Aluminium alkyls and aluminium alkyl halides
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Supplier: Gelest, Inc.
Description: Additional Properties Hydrolytic Sensitivity 1: no significant reaction with aqueous systems Application Mediates photochemical alkylation of heteroaromatic bases with alkyl halides.1 Precursor for CVD of amorphous hydrogenated silicon - carbon films.2 Reference 1. Togo, H. et al.
- Purity: 97 %
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Supplier: Gelest, Inc.
Description: Application Effects free-radical reductive addition of alkyl halides to olefins with AIBN.1,2 Reduces benzylic chlorides 70 X faster than silyl hydrides.3 Initiates radical cyclization of polyenes.4 Reference 1. Hershberger, J. Tetrahedron Lett. 1986, 26, 6289. 2. Pike, P. et al.
- Flash Point: 172.4 F
- Purity: 99 %
- Features: Metalloids (B, Si, Ge, etc.), Non-Metals (C, N, O, P, S)
- Type: OrganoMetallics
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Supplier: Gelest, Inc.
Description: Additional Properties Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents Application Reviews.1,2 Efficient mediator in organic radical reactions.3 Initiates addition of alkyl iodides to activated olefins.4 Initiates and promotes the radical addition of
- Flash Point: 131 F
- Features: Metalloids (B, Si, Ge, etc.), Non-Metals (C, N, O, P, S)
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Supplier: Gelest, Inc.
Description: Additional Properties Hydrolytic Sensitivity 7: reacts slowly with moisture/water Application Cross couples with aryl halides.1 Extensive review on the use in silicon-based cross-coupling reactions.10 Phenylates heteroaromatic carboxamides.2 Directly couples with 1o alkyl bromides and
- Flash Point: 186.8 F
- Purity: 97 %
- Features: Metalloids (B, Si, Ge, etc.), Non-Metals (C, N, O, P, S)
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March's Advanced Organic Chemistry: Reactions Mechanisms and Structure 6th Edition Complete Document
Stable allylic cations have also been obtained by the reaction between alkyl halides , .
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Radicals in Synthesis III
First, chiral N-acylhydrazones are acceptors for intermolecular radical additions of a wide range of primary, secondary, and tertiary alkyl halides to the C¼N bond, with radicals generated under manganese-, tin-, or boron-mediated conditions.
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ACROSS CONVENTIONAL LINES: SELECTED PAPERS OF GEORGE A OLAH (IN 2 VOLUMES)
The Lewis-acid complexes formed by the alkyl halides and catalysts have been .
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Applied Cross-Coupling Reactions
Finally, recent progress is introduced in the form of the new cross-coupling reactions involving aryl chlorides and alkyl halides bearing b-hydrogen as coupling electrophiles.
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Iron Catalysis II
Iron-catalysed cross-coupling reactions are far from new; indeed, the seminal publication in this area dates back over 70 years: a paper published by Motez and Vavon on the iron-catalysed coupling of aryl Grignard reagents with alkyl halides [1].
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Advanced Organic Chemistry
Chapter 1 deals with alkylation of carbon nucleophiles by alkyl halides and tosylates.
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Named Organic Reactions 2nd Edition
The Arbuzov reaction,1–3 also called the Michaelis–Arbuzov reaction, allows for the synthesis of pentavalent alkyl phosphoric acid esters 4 from trivalent phosphoric acid esters 1 (Z,Z0 DR,OR) by treatment with alkyl halides 2.