Adhesives Technology Handbook

5.7: Butyl Rubber Adhesives

5.7 Butyl Rubber Adhesives

Butyl rubber is an elastomeric polymer used widely in adhesives and sealants, both as primary binders and as tackifiers and modifiers. Butyl rubber is a copolymer of isobutylene with a small amount of isoprene.[19] These materials have relatively low strength and tend to exhibit creep under load. They are useful in packaging applications where their low permeability to gases, vapors, and moisture can be exploited. Butyl rubber is also used as an adhesive sealant. It is generally applied from a solvent-based solution. [1 ,5 ] Table 5.1 summarizes some of the important properties of butyl rubber adhesives.

Table 5.1: Properties of Elastomeric Polymers in Non-structural Applications [5]

Adhesives

Natural Rubber (Polyisoprene)

Reclaimed Rubber

Butyl Rubber

Polyisobutylene

Description

Solvent solutions, latexes, and vulcanizing type

Solvent solutions, some water dispersions; most are black, some gray and red

Solvent system, latex

Solvent solution

Curing method

Solvent evaporation, vulcanizing type by heat press RT (two-part)

Evaporation of solvent

Solvent evaporation, chemical cross-linking with curing agents and heat

Evaporation of solvent

Usual adherends

Natural rubber, masonite, wood, felt, fabric, paper, metal

Rubber, sponge rubber, fabric, leather, wood, metal, painted metal, building materials

Rubber, metals

Plastic film, rubber, metal foil, paper

Advantages

Excellent resilience, moisture, and water resistance

Low cost, applied very easily with roller coating, spraying, dipping, or brushing; gains strength rapidly after joining; excellent moisture and water resistance

Excellent aging characteristics; chemically cross-linked materials have good thermal properties

Good aging characteristics; used as tackifiers in other adhesives;

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