Properties, Processing and Applications of Indium Phosphide

Chapter 2: Mechanical, Thermal, Piezoelectric and Electro-Optic Properties

2.1 Density of InP

S. Adachi
April 1998

A INTRODUCTION

The crystal density d is one of the most important material parameters. It can be given by

(1)

where a, M, N A and d M are the lattice parameter, molecular weight of the crystal, Avogadro's constant (6.0221367 10 23 mol -1) and molecular density, respectively. The molecular weight M of InP is 145.7938 g.

B CALCULATED VALUES

If an accurate lattice parameter is available, the calculation of d then gives a good reliable value. Data on the lattice parameter of InP suggest that a = 586.90 pm [1] so that at 300 K


TABLE 1 lists the values of d for temperatures between 4.2 and 600 K, as calculated from EQN (1) with a from [1]. The X-ray d data for T ? 700 K from Brice [2] are also listed in this table.

Table 1: Values of d at various temperatures.

T(K)

d(g/cm 3)

4.2

4.7982

12

4.7982

20

4.7982

29

4.7983

39

4.7984

49

4.7984

59

4.7985

70

4.7985

80

4.7985

90

4.7985

100

4.7984

109

4.7984

119

4.7982

127

4.7979

136

4.7977

156

4.7971

175

4.7963

195

4.7954

214

4.7945

232

4.7936

251

4.7926

272

4.7914

286

4.7909

291

4.7904

300

4.7902

400

4.7836

500

4.7770

600

4.7704

700

4.763

800

4.756

900

4.749

1000

4.742

1100

4.733

1200

4.723

1300

4.712

C MEASURED DATA

TABLE 2 lists the measured values of d taken from [3, 4]. We obtain,...

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