Hazardous Chemicals Handbook, Second Edition

Chapter 8: Cryogens

Overview

Cryogenics, or low-temperature technology, is the science of producing and maintaining very low temperatures usually below 120 K, as distinct from traditional refrigeration which covers the temperature range 120 to 273.1 K. At or below 120 K, the permanent gases including argon, helium, hydrogen, methane, oxygen and nitrogen can be liquefied at ambient pressure as exemplified by Table 8.1. Any object may be cooled to low temperatures by placing it in thermal contact with a suitable liquefied gas held at constant pressure. Applications can be found in food processing, rocket propulsion, microbiology, electronics, medicine, metal working and general laboratory operations. Cryogenic technology has also been used to produce low-cost, high-purity gases through fractional condensation and distillation. Cryogens are used to enhance the speed of computers and in magnetic resonance imaging to cool high conductivity magnets for non-intrusive body diagnostics. Low-temperature infrared detectors are used in astronomical telescopes.

Table 8.1: Properties of common cryogens

Gas

Boiling point ( C)

Volume of gas produced on evaporation of 1 litre of liquid (litres)

Helium

-269

757

Hydrogen

-253

851

Neon

-246

1438

Nitrogen

-196

696

Fluorine

-187

888

Argon

-186

847

Oxygen

-183

860

Methane

-161

578

Krypton

-151

700

Xenon

-109

573

Chlorotrifluoromethane

-81

-

Carbon dioxide

-78.5

553

Every gas has a critical temperature above which it cannot be liquefied by application of pressure alone (Chapter 4). As a result, gases used, e.g., as an inert medium to reduce oxygen content of atmospheres containing flammable gas or vapour (Chapter 6)...

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