Analysis and Design of Vertical Cavity Surface Emitting Lasers

Chapter 4A.2 - Band Structure Model

4A.2 Band Structure Model

In order to calculate the electron and hole wavefunctions in QWs, the multiband effective mass theory is used [22]. For most III-V semiconductor materials sucl as GaAs-based materials, it is a good approximation that the conduction and valence bands are decoupled. A parabolic band model and a Luttinger-Kohr Hamiltonian with strain components are used to calculate the conduction and valence bands, respectively [22]. The electron states near the conduction subband edge are assumed to be almost purely s-like and nondegenerate (excluding spin), while the hole states near the valence subband edge are almost purely p-like and fourfold degenerate (including spin). The envelope function scheme is adopted to describe the slowly varying part of the wavefunction. In the following paragraphs, the slowly varying part of the wavefunction for the electron and hole are calculated.

The influence of QW confinement potential on the energies and envelope functions of the electron subband edge at the zone center of the Brillouin zone can be calculated separately using the one-dimensional Schrödinger-type equation:

where , Ψcl is the envelope function of the lth subband for electrons, m* is the effective mass in the z direction, Ecl is the subband edge energy, and Uc is the QW confinement potential of electrons. This equation can be solved numerically using a finite difference method with the corresponding confinement profile for the approximated parabolic band.

The valence band structure in QWs is more complicated as there is a fourfold degeneracy (including spin degeneracy) at the top of the valence band. The periodic part of the Bloch function (not including the spin degeneracy) at the top of the valence band has the symmetry of a p-type wavefunction that is threefold degenerate. Combining with the spin, there are six valence bands (the heavy hole band, the light hole band, and the spin-orbit splitoff band) just below the conduction band. The spin-orbit splitoff band is split from the heavy hole and light hole bands by the spin-orbit interaction. In addition, the heavy and light hole valence bands are split as a result of the quantum confinement effect. If the energy separation of the spin-orbit splitoff band is far away from the heavy and light hole bands, the corresponding envelope function can be obtained by

where Ψvl is the envelope function of the lth subband for holes, is the Luttinger-Kohn Hamiltonian with strain introduced, and Uv is the confinement potential for hole, which are given by

and the parameters P,Q,R and S are given by




where γ1, γ2, γ3 are the Luttinger-Kohn parameters, which are dependent on the position z and mo is the relative mass of electron. The Luttinger–Kohn Hamiltonian is actually a set of coupled linear differential equations for the envelope functions, which can also be solved using the finite difference approximation.

The periodic part of the Bloch state (basis function) for electrons is given by

where ↑ and ↓ denote the up and down electron spinors and s is the s-like conduction band Bloch states. For holes, the Bloch states are represented by the linear combinations of the products of the spinor and the ρ-like valence band Bloch states px, py, and pz and are given by

When the subband envelope functions are obtained, the optical matrix elements can be calculated by the following expression

where p and q denote the Bloch functions of electron or holes and υp = Ψvl (z) exp(jk · r). Ψ(z) is the envelope function along the z direction, and u is the periodic and rapidly varying part of the Bloch function. A similar expression of cq can also be obtained in a similar manner. The squared of optical matrix elements for the in-plane optical field is obtained within the envelope function approximation

where Ψcp Ψvs,q (for s = – 3/2, –, ,) is the overlap integral of the envelope functions and the expression of Ψvs,q is obtained from the one-dimensional Schrödinger type equation (4A.5).

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