Microfluid Mechanics: Principles and Modeling

Appendix 5B: Additional Energy Carried by Fast Molecules Crossing a Surface

Appendix 5B: Additional Energy Carried by Fast Molecules Crossing a Surface

The flux of molecular quantities across a surface element is considered in an equilibrium gas. The stream velocity c 0 is inclined at the angle ? to the unit normal vector e to the surface element, as shown in Fig. 5B.1. Without loss of generality, Cartesian coordinates are chosen such that the stream velocity lies in the yz-plane, with the x-axis in the negative e direction.


Figure 5B.1: Coordinate system for the analysis of molecular flux across a surface element.

Each molecule has velocity components

(5B.1)

The flux of quantity Q across the surface element along the positive x-direction is

(5B.2)

For an equilibrium gas, the Maxwellian distribution function f 0 is substituted into Eq. (5B.2), and the Q-flux across the element per unit area per unit time can be obtained as

(5B.3)

The number flux of molecules across the surface element is obtained with Q = 1 in Eq. (5B.3).

(5B.4)

where

(5B.5)

The translational energy flux to the element is obtained by setting Q = mc 2 in Eq. (5B.3) to give

(5B.6)

And the averaged translational energy per molecule crossing a surface element is obtained through dividing Eq. (5B.6) by Eq. (5B.4) to give

(5B.7)

where

(5B.8)

Comparing with kinetic theory equation for all the molecules in an equilibrium state with mean flow velocity c 0 and temperature

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