Plasma Source Mass Spectrometry: Applications and Emerging Technologies

Section 4: Preparatory and Delivery Methods

CHAPTER LIST

Chapter 20: A Routine Method for the Dissolution of Geological Samples for the Analysis of REE and Trace Elements Via ICP-MS
Chapter 21: Calculation Methods for the Determination of Isotope Ratios of Transient Signals of Volatile Organometallic Compounds
Chapter 22: The Uncertainty in REE Determination in Urine by ETV-ICP-MS : A New Approach to Data Evaluation
Chapter 23: Trapped Ablation Mode in Laser Ablation ICPMS Experiments for the Enhancement of the Signal-to-noise RATIO

C.J.Ottley, D.G. Pearson and G.J. Irvine [1]

Dept of Geological Sciences, University of Durham, South Rd, Durham, DH1 3LE, UK

1 INTRODUCTION

Most modern ICP-MS laboratories have a large group of users with varying analytical experience who require high quality elemental data from a spectrum of geological sample-types at detection limits of sub PPM level in the solid. Meeting these needs with a single, user-friendly, time-efficient preparation and analysis method is a particular challenge. The method presented here has evolved over several years in our laboratory to be as simple as possible whilst incorporating high quality data objectives, aimed specifically for the analysis of igneous mafic rocks. The data presented represents the typical data quality that can be achieved within one week of commencing this type of work by a user with minimal analytical chemistry background. The protocol forms the basis of more challenging analytical work such as the analysis of acidic rocks and mineral separates to which the operator may progress as required. We illustrate the effectiveness of the technique by reviewing the accuracy...

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