5.1 INTRODUCTION

Cathodic protection is a proven corrosion control method for protection of underground and undersea metallic structures, such as oil and gas pipelines, cables, utility lines and structural foundations. Cathodic protection is now widely applied in the protection of oil drilling platforms, dockyards, jetties, ships, submarines, condenser tubes in heat exchangers, bridges and decks, civil and military aircraft and ground transportation systems.

The designing of cathodic protection systems is rather complex, however, it is based on simple electrochemical principles described earlier in Chapter 2. Corrosion current flows between the local action anodes and cathodes due to the existence of a potential difference between the two (Fig. 5.1). As shown in Fig. 5.2, electrons released in an anodic reaction are consumed in the cathodic reaction. If we supply additional electrons to a metallic structure, more electrons would be available for a cathodic reaction which would cause the rate of cathodic reaction to increase and that of anodic reaction to decrease, which would eventually minimize or eliminate corrosion. This is basically the objective of cathodic protection. The additional electrons are supplied by direct electric current. On application of direct current, the potential of the cathode shifts to the potential of the anodic area. If sufficient direct current is applied, the potential difference between the anode and cathode is eliminated and corrosion would eventually cease to occur.

Figure 5.1: An electrochemical cell. Corrosion cell between two areas on single metal surface. Current flows because of a potential difference that exists between anode...