Principles of Corrosion Engineering and Corrosion Control

Chapter 12: Concrete Corrosion

12.1 INTRODUCTION

Concrete is the most widely used constructional material in the world. In spite of the impressive performance of concrete in several structures, the deterioration of concrete has assumed alarming proportion in harsh climatic conditions, such as the sea-coastal areas in Gulf countries. Concrete can be defined as the artificial stone produced when cement (usually Portland cement) is mixed with fine aggregate (sand), a coarse aggregate (gravel or crushed stones) and water.

12.1.1 APPLICATIONS

The intended application of concrete dictates the proportioning of major concrete ingredients, cement type, as well as particle size gradations of the fine coarse aggregates. Concrete generally provides to embedded steel a high degree of protection against corrosion by providing a highly alkaline environment which passivates the steel against corrosion. Corrosion of reinforcing steel can, however, proceed in some environments, suchasamarineenvironment, duetothepresence of chloride.

12.2 TECHNICAL TERMS

Definitions and a brief explanation of important terms related to concrete are given below to familiarize engineers with the applications of concrete.

12.2.1 AGGREGATES

Aggregates used in normal construction comprise granular materials, like limestone, dolomite, gravel, silica, etc. Table 12.1 shows the effect of properties and characteristics of aggregates which affect the characteristics of concrete. The salts in the aggregates, such as sulfates, chlorides and carbonates of calcium, magnesium and sodium, contribute to the corrosion of concrete.

Table 12.1: Properties of concrete which are influenced by properties and characteristics of the aggregates

Concrete property

Relevant aggregate property

Durability:


Soundness
Porosity

Resistance to freezing and thawing

Pore structure
Permeability

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