Membrane Separations Technology: Single-Stage, Multistage, and Differential Permeation

Appendix 1: Representative Membrane Permeabilities and Selectivities

Overview

The information provided in the following tables is an assortment of permeability and selectivity values or their alternatives, as per the presentation of the subject in Chapter 1.As the concluding tabulation, in Table A1.23, this information is condensed into spreadsheet representation of selected membrane permeability for various components and membrane materials.

Table A1.1: Permeability of Solids to Hydrogen at Elevated Temperatures

System

Temp.( C)

10 ?6cm 2/sec-atm

10 ?9cm 2/sec-atm

10 ?9cm 2/sec-cm Hg

H-Cu

500

3.5

3,500

46.1

750

8

8,000

105

H-Fe

500

100

100,000

1,316

600

336

Etc.

4,421

H-Ni

500

3.8

50

750

31.6

416

H-Pd

500

4,450

58,550

600

5,750

75,660

H-Pt

600

0.77

0.1

800

4.8

63.2

H-Zn

300

0.4

5.3

H-rubber

20

0.3

3.9

100

2.6

34.2

H-SiO2

500

6.2-28

0.08-0.37

800

35-100

0.46-1.3

H-Pyrex

600

Inappreciable

Inappreciable

Source: Adapted from the International Critical Tables, vol. V, pp.76-77.

Table A1.2: Gas Permeabilities and Selectivity for Different Membranes

Membrane

P He

P N 2

P CH 4

He/N 2

He/CH 4

Silicone

23

15

59

1.5

0.39

Phenyl silicone

15

4.0

20

3.8

0.75

Nitrile silicone

7.9

2.1

10

3.8

0.79

Polycarbonate

6.7

0.46

0.36

15

19

Teflon

6.2

0.25

0.14

25

44

Natural rubber

3.6

1.05

3.4

Polystyrene

3.5

0.22

0.23

16.0

15

Triethene B

3.4

0.012

0.0084

280

400

Ethyl cellulose

3.1

0.28

0.64

11

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