SiC Materials and Devices, Volume 2

T. Paul Chow
Center for Integrated Electronics
Rensselaer Polytechnic Institute, Troy, New York 12180, U.S.A.
and
Anant K. Agarwal
Cree, Durham, NC 27703, U.S.A.
Silicon has long been the dominant semiconductor of choice for high-voltage power electronics applications.1 ,2 However, recently, wide bandgap semiconductors, particularly SiC and GaN, have attracted much attention because they are projected to have much better performance than silicon and the epi/substrate technology has matured to make device commercialization possible. 3 7 Compared to silicon, these wide bandgap semiconductors, SiC, GaN and InN can be categorized into one group while diamond, BN and AIN into another because the former has bandgaps of 2 3.5 eV and the latter 5.5 6.5 eV. Group IV or IV-IV semiconductors have indirect bandgaps whereas most of the Group III-nitrides are direct (except BN). The superior physical properties of these semiconductors offer a lower intrinsic carrier concentration (10 to 35 orders of magnitude), a higher electric breakdown field (4 20 times), a higher thermal conductivity (3 13 times), a larger saturated electron drift velocity (2 2.5 times), when compared to silicon (See Table 1). SiC has over 150 polytypes (which are different crystal structures with the same stoichiometry of a compound semiconductor). Also, only the 6H- and 4H-SiC polytypes are available commercially in both bulk wafers (up to 4" in diameter at present) and custom epitaxial layers (up to at least 100 ?m at present) while 3C-SiC is available as heteroepitaxial layers on large-diameter silicon substrates. Between the two polytypes, 4H-SiC has...