Semiconductor Nanostructures for Optoelectronic Applications

Chapter 7: Antimony-Based Materials for Electro-Optics

Wei Zhang and M. Razeghi, Center for Quantum Devices, Northwestern University

7.1 Introduction

7.1.1 Antimony

Antimony (Sb) is a semimetal and has an atomic number of 51 and atomic weight of 121.760. It is located in group 15 (V-A) and period 5 in the chemical periodic table. Antimony is solid at room temperature and standard state. In its elemental form it is a silvery white, brittle crystalline solid. It is not acted on by air at room temperature, but burns brilliantly when heated and forms white fumes. It is a poor conductor of heat and electricity. The physical data for antimony are summarized in Table 7.1.

Table 7.1: Summary of Physical Data for Antimony

Symbol

Sb

Atomic number

51

Atomic weight

121.760 amu

Steric

Atomic radius

1.53

Ionic radiu

0.76k

Covalent radius

1.40

Atomic volume

18.23cm 3/mol

Density (293K)

6.684 g/cm 3

Crystal structure

Rhombohedral

Electronic

Shells

2,8,18,18,5

Orbitals

[Kr] 4d 10 5s 2 5p 3

Electronegativity

1.8, 1.9

Oxidation states

5, 3, -3

Electrical resistivity

4 10 -7 ?m

Thermal

Melting point

630.74 C

Boiling point

1,587 C

Specific heat

0.21 J/g K

Heat of fusion

19.870 kJ/mol

Heat of vaporization

77.140 kJ/mol

Thermal conductivity

0.243 W/cm K

Antimony has been known and used since ancient times. The name antimony comes from the Greek words anti + monos, meaning "not alone," because it is often found in ores such...

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