Vacuum Deposition onto Webs, Films, and Foils

Part 2: Substrates, Surface Modification, and Nucleation

Chapter List

Chapter 8: Substrates Surface Quality, Cleaning Adhesion and Adhesion Testing
Chapter 9: Surface Treatment of Webs and Foils
Chapter 10: Nucleation, Coalescence, and Film Growth

8.1 Substrates

The bulk of roll coating processes utilize polymer webs and these are dealt with first in this chapter.

8.1.1 Polymer Roll Quality

Polymer webs produced by the stenter or bubble process and that are biaxially oriented can be made up to 10 m wide. [1 ,2 ] Metallizers are frequently much less than this, anywhere from less than 1 m wide for some capacitor machines to as much as 3.5 m wide for some simple packaging metallizers. Most will be somewhere between 2 and 2.5 m wide. This means that the mill roll produced at the stenter has to be slit into narrower rolls. The more times the rolls are rewound or slit the more chances of winding defects[3] occurring and the greater the quantity of debris attached to the surfaces. Some of the possible defects and causes are described here.

The stress within the web is not uniform (Fig. 8.1) although it is often symmetric about the web centerline. This can mean that there are differences between webs that are slit from the edges of the mill rolls and those that are slit from the center of the mill rolls.


Figure 8.1: The figures show some of the problems that occur with a web that is longer in the middle (LIM) or shorter in the middle (SIM) as a...

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