Bretherick's Handbook of Reactive Chemical Hazards, Volume 2, Seventh Edition

DEFLAGRATION INCIDENTS DUST EXPLOSION INCIDENTS

DEFLAGRATION INCIDENTS

Some incidents involving deflagration may be found under:

  • Ammonium dichromate, 4240

  • 4-Chloronitrobenzene, 2135

  • 1-(2,4-Dinitrobenzeneazo)-2-hydroxynaphthalene, 3695

  • Hydroxylaminium sulfate, 4570

  • 4-Nitrobenzoic acid, 2691

  • 2-Nitrosophenol (1,2-Benzoquinone monoxime), 2256

  • Sodium 3-nitrobenzenesulfonate, 2177

See entry CRITICAL IGNITION TEMPERATURE, PRESSURE INCREASE IN EXOTHERMIC DECOMPOSITION (reference 3)

DEFLAGRATION TO DETONATION

Chatrathi, K. et al., Process Safety Progr., 1996, 15(4), 237

A study of deflagration to detonation transition in pipes, for gas/air and dust mixtures, has been made and reported. Obviously it depends upon the exact mixture, but departures from the straight and narrow generally facilitate this transition from slight to seriously destructive over-pressures.

See also DUST EXPLOSION INCIDENTS, GEOMETRY OF VESSELS AND PIPEWORK, VAPOUR CLOUD EXPLOSIONS

DEVARDA'S ALLOY Cu Al Z n

  1. Cameron, W. G., Chem. & Ind., 1948, 158

  2. Chaudhuri, B. B., Chem. & Ind., 1948, 462

The analytical use of the alloy to reduce nitrates is usually accompanied by the risk of a hydrogen explosion, particularly if heating is effected by flame. Use of a safety screen and flameless heating, coupled with displacement of hydrogen by an inert gas, are recommended precautions [1]. The explosion was later attributed to gas pressure in a restricted system [2].

See other ALLOYS, GAS EVOLUTION INCIDENTS

DIACYL PEROXIDES RCO.OOCO.R, RSO 2.OOSO.R 2

  1. Swern, 1970, Vol. 1,70

  2. Mageli, O. L. et al., US Pat. 3 956 396, 1976

  3. Fujimori, K., Org. Peroxides, Chichester, John Wiley, 1992, 319

Most of the isolated diacyl (including sulfonyl) peroxides are...

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