2006 ASHRAE Handbook: Refrigeration, Inch-Pound Edition

Cryogenics is a term normally associated with low temperatures. However, the location on the temperature scale at which refrigeration generally ends and cryogenics begins has never been well defined. Most scientists and engineers working in this field restrict cryogenics to a temperature below ?235 F (225 R), because the normal boiling points of most permanent gases (e.g., helium, hydrogen, neon, nitrogen, argon, oxygen, and air) occur below this temperature. In contrast, most common refrigerants have boiling points above this temperature.
Cryogenic engineering therefore is involved with the design and development of low-temperature systems and components. In such activities the designer must be familiar with the properties of fluids used to achieve these low temperatures as well as the physical properties of components used to produce, maintain, and apply such temperatures.
The application of cryogenic engineering has become extensive. In the United States, for example, nearly 30% of the oxygen produced by cryogenic separation is used by the steel industry to reduce the cost of high-grade steel, and another 20% is used in the chemical process industry to produce a variety of oxygenated compounds. Liquid hydrogen production has risen from laboratory quantities to over 200 tons/day. Similarly, liquid helium demand has required the construction of large plants to separate helium from natural gas cryogenically. Energy demand likewise has accelerated construction of large base-load liquefied natural gas (LNG) plants. Applications include high-field magnets and...