Statistical Thermodynamics: Fundamentals and Applications

Appendix H: Review of Operator Theory

An operator is a mathematical rule, or set or rules, which transforms one function into another without necessarily specifying any particular function. Mathematically, we define the general operator, , as


Examples of might be (1) multiply by x or (2) take the first derivative with respect to x. In the first case, is simply x and g( x) = xf( x) . In the second case, is d/ dx and g( x) = df( x)/ dx.

Some of the basic rules of operator algebra are as follows:

(H.1)
(H.2)
(H.3)
(H.4)
(H.5)

where C is a constant. The identity operator, , is the operator which leaves the function unchanged; the null operator, , is the operator which yields zero when operating on any function:

(H.6)
(H.7)

Note that, in Eqs. (H.4) and (H.5), we dropped any explicit reference to the function f( x) . This is the usual way of writing the equations of operator algebra.

Most operators encountered in the physical sciences are linear operators. An operator, , is linear if

(H.8)

An example of a nonlinear operator is the square-root execution. In general, the results from two operations do not commute, so that = . Hence, if we define the commutator, [ , ], as

(H.9)

the operators and can...

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