EIT Chemical Review, Second Edition

Chapter 2: Material and Energy Balances

Overview

ACCOUNTING PRINCIPLE: This can be expressed by the equation:

Q E - Q B = ? Q I - ? Q O + ?Q P

where

Q

=

physical quantity chosen for accounting

Q E

=

the quantity at end of accounting period

Q B

=

the quantity at the beginning of the accounting period

Q I

=

the quantity which enters the system during accounting period

Q O

=

the quantity which leaves the system during accounting period

Q P

=

Quantity created or destroyed during accounting period

In ordinary processes involving chemical (not nuclear) reactions, ?Q P = 0 If the quantity in the system does not change with time , Q E - Q B = 0 and the accounting equation reduces to ?Q I - ?Q O = 0. In this case, input equals output. The system is said to be under steady state condition. The accounting principle can also be used to make an energy balance for a system. In carrying out mass and energy balances, several definitions and relations about different properties of substances are useful. These are:

Density of a substance, ? = mass/volume and Specific gravity of a substance, s = ?/ ? r

where ?r is the density of the reference substance. For liquids and solids, water is usually the reference substance at 4 C( ? = 1000...

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