Handbook of Optics: Devices, Measurements, and Properties, Volume II, Second Edition

Chapter 28: SPECTROSCOPIC MEASUREMENTS

Brian Henderson

Department of Physics
and Applied Physics
University of Strathclyde
Glasgow, United Kingdom

28.1 GLOSSARY

A ba

Einstein coefficient for spontaneous emission

a 0

Bohr radius

B if

Einstein coefficient between initial state and final state

e

charge on the electron

ED

electric dipole term

E DC

Dirac Coulomb term

E hf

hyperfine energy

E n

eigenvalues of quantum state n

EQ

electric quadrupole term

E( t)

electric field at time t

E( ?)

electric field at frequency ?

g a

degeneracy of ground level

g b

degeneracy of excited level

g N

gyromagnetic ratio of nucleus

h

Planck's constant

H so

spin-orbit interaction hamiltonian

I

nuclear spin

I( t)

the emission intensity at time t

j

total angular momentum vector given by j = 1

l i

orbital state

m

mass of the electron

MD

magnetic dipole term

M N

mass of nucleus N

n ?( T)

equilibrium number of photons in a blackbody cavity radiator at angular frequency ? and temperature T

QED

quantum electrodynamics

R nl( r)

radial wavefunction

R ?

Rydberg constant for an infinitely heavy nucleus

s

spin quantum number with the value 1/2

s i

electronic spin

T

absolute temperature

W ab

transition rate in absorption transition between states a and b

W ba

transition rate in emission transition from state b to state a

Z

charge on the nucleus

fine structure constant

? ?

natural linewidth...

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