Applied Quantum Mechanics, Second Edition

Chapter 2: Toward Quantum Mechanics

2.1 Introduction

It is believed that the basic physical building blocks forming the world we live in may be categorized into particles of matter and carriers of force between matter. All known elementary constituents of matter and transmitters of force are quantized. For example, energy, momentum, and angular momentum take on discrete quantized values. The electron is an example of an elementary particle of matter, and the photon is an example of a transmitter of force. Neutrons, protons, and atoms are composite particles made up of elementary particles of matter and transmitters of force. These composite particles are also quantized. Because classical mechanics is unable to explain quantization, we must learn quantum mechanics in order to understand the microscopic properties of atoms which, for example, make up solids such as crystalline semiconductors.

Historically, the laws of quantum mechanics have been established by experiment. The most important early experiments involved light. Long before it was realized that light waves are quantized into particles called photons, key experiments on the wave properties of light were performed. For example, it was established that the color of visible light is associated with different wavelengths of light. Table 2.1 shows the range of wavelengths corresponding to different colors.

Table 2.1: Wavelengths of visible light

Wavelength (nm)

Color

760 622

red

622 597

orange

597 577

yellow

577 492

green

492 455

blue

455 390

violet

The connection between optical and electrical phenomena was established by Maxwell...

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