Binary Distillation; the McCabe-Thiele Method
In the case of a continuous distillation column (see Figure 5-8) a method used to determine the number of ideal stages is the McCabe-Thiele.
Figure 5-8: Schematic of continuous distillation column. Section above feed is enriching or rectifying; below feed is stripping section. (Reproduced with permission from reference 38. Copyright 1997 American Chemical Society.)
The stages in a distillation column can be of various configurations. Two systems are shown in Figure 5-9.
Figure 5-9: Bubble cap ( a and b) and sieve plate ( c). Adapted from 36, 37.
The enthalpy balance for the McCabe-Thiele in the rectifying section essentially reduces to the vapor streams entering and leaving a stage V in moles/time and ?, the enthalpy of vaporization.
(5-13) | |
For chemically similar materials,
(5-14) | |
and
(5-15) | |
This gives a condition known as constant molal overflow (i.e., all the V's in the rectifying section including V a are equal; the same holds true for all the L's including L a). The same condition holds for the stripping section (all vapor streams including V b are equal and all L streams are equal to each other).
A mass balance for the rectifying section gives
(5-16) | |
or
(5-17) | |
Likewise, the mass balance for the stripping section is
(5-18) | |
or
(5-19) | |
Equations 5-16 through 5-19 are straight lines because of constant molal overflow.
The junction of the rectifying and stripping mass balances is fixed by the feed...