Electronics Manufacturing: With Lead-Free, Halogen-Free, and Conductive-Adhesive Materials

14.7: Pd

14.7 Pd

Palladium (Pd) is an attractive, cost-effective alternative finish for printed wiring boards (PWBs) that is both solderable and wire bondable. Similar to gold, Pd is a noble metal; therefore, it is stable against many chemical reactions, such as oxidation. In addition, Pd exhibits several advantages over Au as a potential surface finish constituent:

  1. Pd is cheaper than Au.

  2. Pd exhibits a density 38 percent lower than Au (12.02 versus 19.32 g/cm 3), thus further reduces the cost of Pd needed for surface finish applications.

  3. Pd displays a tensile strength about 35 percent higher than Au.

  4. Pd exhibits a hardness at 250 to 290 Vickers, about twice that of copper and three times that of gold, thus making it more suitable for contact purposes.

  5. Pd dissolves in molten 60Sn-40Pb at a much lower rate than Au (about 0.01 versus 5 m/s), thus it is less prone to contaminate the solder pot.66 ,67

14.7.1 ELECTROLYTIC Pd WITH OR WITHOUT IMMERSION Au

Electrolytic Pd or electrolytic Pd with Au flash provides a thin deposit on top of copper. The Pd is less than 0.5 m, and is typically 0.25 m in thickness. The Au flash is 0.025 m in thickness. The fabrication process is described in the following subsection.

Fabrication Process. The electrolytic Pd plating process is integrated with the PCB patterning process as follows:

  1. Cu plate

  2. Pd plate

  3. Resist strip

  4. Cu etch

  5. Solder mask application

During the plating cycle, Pd is applied immediately after acid copper...

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Category: Electrolytic Cleaning Equipment
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