Fundamentals of Quantum Mechanics: For Solid State Electronics and Optics

Chapter 2: Basic Postulates and Mathematical Tools

Basic scientific theories usually start with a set of hypotheses or postulates. There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from revelations in the minds of geniuses, most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the state functions, operators, and equations of motion.

In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics. The full interpretation, and the power and...

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