Gas Well Deliquification

Appendix C: Gas Fundamentals

C.1 Introduction

This Appendix catalogs some commofnly used gas fundamental expressions that are useful when operating gas wells.

C.2 Phase Diagram

A hydrocarbon gas is a mixture of different hydrocarbon molecules in varying composition. The type and amount ofeach molecular species in the gas determines the mixture properties at a given pressure and temperature.

As shown in Figure C-1, Critical temperature (T C) is the temperature of a gas above which it cannot be liquefied by increasing pressure.


Figure C-1: Typical gas well reservoir phase diagram

Critical pressure (P C) is the pressure a gas exerts when in equilibrium with the liquid phase at the critical temperature.

Critical volume (V C) is the volume of one pound of gas at the critical temperature and pressure.

Cricondenbar is the highest pressure at which a gas can exist. Cricondenterm is the highest temperature at which a liquid can exist. Bubble point is the pressure at a given temperature above which the mixture is 100% liquid. Dew point is the pressure, at a given temperature, above which the mixture is 100% gas.

C.3 Gas Apparent Molecular Weight and Specific Gravity

Molecular weight is defined for a specific molecule but not for a mixture of different molecular species. For gas mixtures, the apparent gas molecular weight M is defined to represent the average molecular weight of all the molecules in the gas. Thus, M


where y j = mole fraction of molecule j

M j = molecular weight...

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