Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition

Serial No. 0251 0500

0251. Ammonium Bromide [12124-97-9] BrH 4N

Bromine Trifluoride

See Bromine trifluoride: Ammonium halides

See related METAL HALIDES

0252. Ammonium Bromate [13483-59-5] BrH 4NO 3

  1. Sorbe, 1968, 129

  2. Shidlovskii, A. A. et al., Chem. Abs., 1968, 69, 78870

It is a combustible and explosive salt which is very friction-sensitive [1], and may explode spontaneously [2].

Other Reactants

Yoshida, 1980, 180

MRH values calculated for 16 combinations with oxidisable materials are given.

See other OXOSALTS OF NITROGENOUS BASES

0253. Poly(dimercuryimmonium Bromate) [ ] (BrHg 2NO 3) n

Sorbe, 1967, 97

Highly explosive.

See entry POLY(DIMERCURYIMMONIUM) COMPOUNDS

0254. Iodine Bromide [7789-33-5] BrI


Metals

  1. Mellor, 1961, Vol. 2, Suppl. 2, 452; 1963, Suppl. 3, 1563

  2. Pascal, 1963, Vol. 8.3, 308

A mixture with sodium explodes under a hammer blow, while potassium explodes strongly under the molten bromide [1]. Tin reacts violently with the bromide [2].

Phosphorus

Mellor, 1963, Vol. 2, Suppl. 3, 264

Phosphorus reacts violently with the molten bromide

See other INTERHALOGENS, IODINE COMPOUNDS

0255. Potassium Bromate [7758-01-2] BrKO 3

HCS 1980, 760

Anon., Personal communication, 1999

A factory using potassium bromate regularly in small portions found that it caked in storage and had to be broken up. A largely full, but year old, polythene lined fibre-board drum thereof was broken by stabbing the contents with a, possibly rusty, knife and the lumps needed for use removed by gloved hand. The 1.5 kg so removed was observed to be fizzing and was sprayed...

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