Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition


See Bromine trifluoride: Ammonium halides
See related METAL HALIDES

Sorbe, 1968, 129
Shidlovskii, A. A. et al., Chem. Abs., 1968, 69, 78870
It is a combustible and explosive salt which is very friction-sensitive [1], and may explode spontaneously [2].
Yoshida, 1980, 180
MRH values calculated for 16 combinations with oxidisable materials are given.
See other OXOSALTS OF NITROGENOUS BASES

Sorbe, 1967, 97
Highly explosive.
See entry POLY(DIMERCURYIMMONIUM) COMPOUNDS
Mellor, 1961, Vol. 2, Suppl. 2, 452; 1963, Suppl. 3, 1563
Pascal, 1963, Vol. 8.3, 308
A mixture with sodium explodes under a hammer blow, while potassium explodes strongly under the molten bromide [1]. Tin reacts violently with the bromide [2].
Mellor, 1963, Vol. 2, Suppl. 3, 264
Phosphorus reacts violently with the molten bromide
See other INTERHALOGENS, IODINE COMPOUNDS

HCS 1980, 760
Anon., Personal communication, 1999
A factory using potassium bromate regularly in small portions found that it caked in storage and had to be broken up. A largely full, but year old, polythene lined fibre-board drum thereof was broken by stabbing the contents with a, possibly rusty, knife and the lumps needed for use removed by gloved hand. The 1.5 kg so removed was observed to be fizzing and was sprayed...