Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition

Serial No. 1251 1500

1251. Azetidine [503-29-7] C 3H 7N

Dinitrogen Pentaoxide

See Dinitrogen pentaoxide: Strained ring heterocycles

See other STRAINED-RING COMPOUNDS

1252. Cyclopropylamine [765-30-0] C 3H 7N

1253. 2-Methylaziridine (Propyleneimine) [75-55-8] C 3H 7N

Acids

Inlow, R. O. et al., J. Inorg. Nucl. Chem., 1975, 37, 2353

Like the lower homologue ethyleneimine, it may polymerise explosively if exposed to acids or acidic fumes, so it must always be stored over solid alkali.

See other POLYMERISATION INCIDENTS

1254. Acetone Oxime (2-Hydroxyiminopropane) [127-06-0] C 3H 7NO

Energy of decomposition (in range 200 420 C) measured as 1.5 kJ/g.

See entry THERMOCHEMISTRY AND EXOTHERMIC DECOMPOSITION (reference 2)

See other OXIMES

1255. Dimethylformamide [68-12-2] C 3H 7NO

HCS 1980, 430; RSC Lab. Hazard Data Sheet No.17, 1983

This powerful aprotic solvent is not inert and reacts vigorously or violently with a range of materials.

See endo-2,5-Dichloro-7-thiabicyclo[2.2.1]heptane: Dimethylformamide

Diisocyanatomethane: Dimethylformamide

Lithium azide: Alkyl nitrates, etc.

Sodium hydride: Dimethylformamide

Sodium tetrahydroborate: Dimethylformamide

Sodium: Dimethylformamide

Sulfinyl chloride: Dimethylformamide

Tetraphosphorus decaoxide: Organic liquids

2,4,6-Trichloro-1,3,5-triazine: Dimethylformamide

Triethylaluminium: Dimethylformamide

Allyl Trifluoromethanesulfonates

See ALLYL TRIFLUOROMETHANESULFONATES: Alone, or Aprotic solvents

3-Chloroperoxybenzoic Acid

See 3-Chloroperoxybenzoic acid

Halocarbons

1,2,3,4,5,6-Hexachlorocyclohexane: Dimethylformamide

See Carbon tetrachloride: Dimethylformamide

See N,N-Dimethylacetamide: Halogenated compounds, etc.

See other CATALYTIC IMPURITY INCIDENTS

Other Reactants

Yoshida, 1980, 172

MRH values calculated for 13 combinations with oxidants are given.

Oxidants

Pal, B. C. et al., Chem. Eng. News, 1981, 59(17), 47

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