2001a. Tetramethylammonium Azidoselenocyanatoiodate(I) [ ] C ₅H ₁₂IN ₅Se

See Tetramethylammonium azidocyanoiodate(I)

See related METAL AZIDES, METAL CYANATES

2001b. Di( N-Lithiomethyl- N-Methylamino)Methane [ ] C ₅H ₁₂Li ₂N ₂

Denk, M. K. et al., Chem. Eng. News, 2003, 81(26) 2

This compound exploded during vacuum drying. It is considered that solvation may be a stabilising factor and drying should be avoided.

2002. Dimethylthallium N-Methylacetohydroxamate [57812-15-4] C ₅H ₁₂NO ₂Tl

Schwering, H. U. et al., J. Organomet. Chem., 1975, 99, 22

It exploded below 160 C, without melting, unlike the other dialkyl- gallium and indium derivatives, which showed notable thermal stability.

See other N O COMPOUNDS

2003. O, O-Dimethyl S-Methylcarbamoylmethyl Phosphorodithioate [60-51-5] C ₅H ₁₂NO ₃PS ₂

1. Matos, E. et al., Chem. Abs., 1983, 98, 94955

2. Ludovisi, G, et al. in Safety and Runaway Reactions, Smeder, B & Mitchison, N. (Eds.), EUR 17723 EN, European Commission, 1997, p11

Accidental exothermic decomposition of the insecticide Dimethoate in a 60001 vessel led to gross contamination; (no further details of circumstances available from author) [1]. A second incident of bulk decomposition in cyclohexanone solution (concentration not given) is slightly better reported. This was a formulation solution; the details of the processing are not clear from the report but appear to have involved azeotroping the dimethoate dry, then discharging the warm solution (no temperatures given) to the insulated, uncooled, storage vessel which...