Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition

Serial No. 1751 2000

1751. Bis(dimethylamino) Sulfoxide [3768-60-3] C 4H 12N 2OS

Sulfinyl Chloride

See Sulfinyl chloride: Bis(dimethylamino) sulfoxide

See other N S COMPOUNDS

1752. Seleninyl Bis(dimethylamide) [2424-09-1] C 4H 12N 2OSe

Bailar, 1973, Vol. 2, 975

Vacuum distillation at temperatures around 50 60 C leads to explosive decomposition.

See related N-METAL DERIVATIVES, N S COMPOUNDS

1753. Tetramethyl-2-tetrazene [6130-87-6] C 4H 12N 4

  1. Houben-Weyl, 1967, Vol. 10.2, 830

  2. Stull, 1977, 22

It explodes above its b.p., 130 C/1 bar [1], and is strongly endothermic ( +226.4 kJ/mol, 1.98 kJ/g) [2].

See other ENDOTHERMIC COMPOUNDS, TETRAZENES

1754. Dihydrazinenickel(II) Succinate (Bis(hydrazine)[butanedioato(2 )]nickel) [45101-14-2] C 4H 12N 4NiO 4

See HYDRAZINE METAL MALONATES AND SUCCINATES

1755. Bis(dimethylstibinyl) Oxide [ ] C 4H 12OSb 2

Sidgwick, 1950, 777

It ignites in air.

See related ALKYLMETALS

1757. Diethylhydroxytin Hydroperoxide [ ] C 4H 12O 3Sn

Bailar, 1973, Vol. 2, 68

It is explosive.

See other ORGANOMETALLIC PEROXIDES

1758a. Tetramethoxysilane (Tetramethyl Silicate) [681-84-5] C 4H 12O 4Si

HCS 1980, 662

Metal Hexafluorides

Jacob, E., Angew. Chem. (Intern. Ed.), 1982, 21, 143, (footnote 6)

During the preparation of the hexamethoxides of rhenium, molybdenum and tungsten by co-condensation with excess tetramethoxysilane on a cold surface, simultaneous co-condensation is necessary to avoid the danger of explosion present when sequential condensation of the reactants is employed. In the latter case, the high concentration of hexafluoride at the interface leads to violent reaction with the...

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