Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition


See Sulfinyl chloride: Bis(dimethylamino) sulfoxide
See other N S COMPOUNDS

Bailar, 1973, Vol. 2, 975
Vacuum distillation at temperatures around 50 60 C leads to explosive decomposition.
See related N-METAL DERIVATIVES, N S COMPOUNDS

Houben-Weyl, 1967, Vol. 10.2, 830
Stull, 1977, 22
It explodes above its b.p., 130 C/1 bar [1], and is strongly endothermic (
+226.4 kJ/mol, 1.98 kJ/g) [2].
See other ENDOTHERMIC COMPOUNDS, TETRAZENES

See HYDRAZINE METAL MALONATES AND SUCCINATES
Sidgwick, 1950, 777
It ignites in air.
See related ALKYLMETALS

Bailar, 1973, Vol. 2, 68
It is explosive.
See other ORGANOMETALLIC PEROXIDES

HCS 1980, 662
Jacob, E., Angew. Chem. (Intern. Ed.), 1982, 21, 143, (footnote 6)
During the preparation of the hexamethoxides of rhenium, molybdenum and tungsten by co-condensation with excess tetramethoxysilane on a cold surface, simultaneous co-condensation is necessary to avoid the danger of explosion present when sequential condensation of the reactants is employed. In the latter case, the high concentration of hexafluoride at the interface leads to violent reaction with the...