Bretherick's Handbook of Reactive Chemical Hazards, Volume 1, Seventh Edition


Anon., Jahresber., 1978, 75
Treatment of the citrate monohydrate with a 20% excess of 70% hydrogen peroxide gave a crystalline product which, after vacuum drying at 50 C corresponded approximately to the tri(hydrogen peroxidate). It decomposed violently when disturbed with a porcelain spatula.
See other CRYSTALLINE HYDROGEN PEROXIDATES

See Lithium: Bromobenzene
Gilman, H. et al., J. Org. Chem., 1945, 10, 507
The product of interaction at 0 C (of unknown composition) ignited in air and reacted violently with water.
See other ARYLMETALS

Willst tter, R. et al., Ber., 1906, 37, 4607
The solid decomposes with near-explosive violence.
See related DIENES

Energy of decomposition (in range 190 380 C) measured as 0.823 kJ/g.
See entry THERMOCHEMISTRY AND EXOTHERMIC DECOMPOSITION (reference 2)
See other NITROSO COMPOUNDS

( MCA SD-21, 1967); HCS 1980, 681; 32RSC Lab Hazards Data Sheet No. 77, 1988
CHETAH, 1990, 182
It is marginally detonable; requiring a 50 g tetryl booster.
The heat of decomposition of nitrobenzene was determined (360 490 C) as 1.76 kJ/g by DSC, and T ait24 was as 280 C by adiabatic Dewar tests, with an apparent energy of activation of 216 kJ/mol.