Industrial Chemical Process Design

Chapter 7: Liquid-Liquid Extraction

Nomenclature

? ?

density difference between liquid phases, lb/ft 3

a

packing area, ft 2/ft 3

D C

continuous-phase density, lb/ft 3

D D

dispersed-phase density, lb/ft 3

DIA 1

extractor internal diameter, column section 1, ft

DIA 1 R

required extractor column internal diameter for raffinate phase, ft

DIA 1 S

required extractor column internal diameter for solvent phase, ft

F e

packing factor

FLOOD R 1

extractor loading flood percentage, raffinate flow rate basis

FLOOD S 1

extractor loading flood percentage, solvent flow rate basis

H

Henry s law constant, atm/mole fraction of solute in liquid phase

H f

Henry s law constant for solute in feed liquid phase

H s

Henry s law constant for solute in solvent liquid phase

K D

equilibrium constant; distribution coefficient

MW f

molecular weight of feed without solute

MW s

molecular weight of solvent without solute

O j

interfacial surface tension from Fig. 7.12, dyn/cm


Figure 7.12: Trebal correlation for interfacial tension. XAB, mole fraction of raffinate dissolved in solvent; XBA, mole fraction of solvent dissolved in raffinate; XCA, mole fraction of solute dissolved in raffinate; XCB, mole fraction of solute dissolved in solvent.

p

partial pressure of solute, atm

RDEN 1

raffinate density, column section 1, lb/ft 3

S

entering solvent, lb

S 1

solvent rate, column section 1 (solute included), lb/h

SDEN 1

solvent density, column section 1,...

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