TABLE OF CONTENTS Tiberiu M. Leib, Ph.D. Principal Consultant, DuPont Engineering Research and Technology, E. I. du Pont de Nemours and Company; Fellow, American Institute of Chemical Engineers
Carmo J. Pereira, Ph.D., MBA DuPont Fellow, DuPont Engineering Research and Technology, E. I. du Pont de Nemours and Company; Fellow, American Institute of Chemical Engineers
| REFERENCES | ||
| BASIC CONCEPTS | ||
| Mechanism | 7-5 | |
| Reaction Rate | 7-5 | |
| Classification of Reactions | 7-5 | |
| Effect of Concentration on Rate | 7-6 | |
| Law of Mass Action | 7-6 | |
| Effect of Temperature | 7-6 | |
| Heat of Reaction | 7-6 | |
| Chemical Equilibrium | 7-7 | |
| Conversion, Extent of Reaction, Selectivity, and Yield | 7-7 | |
| Concentration Types | 7-8 | |
| Stoichiometric Balances | 7-8 | |
| Single Reactions | 7-8 | |
| Reaction Networks | 7-9 | |
| Catalysis | 7-9 | |
| IDEAL REACTORS | ||
| Ideal Batch Reactor | 7-11 | |
| Batch Reactor (BR) | 7-11 | |
| Semibatch Reactor (SBR) | 7-12 | |
| Ideal Continuous Stirred Tank Reactor (CSTR) | 7-12 | |
| Plug Flow Reactor (PFR) | 7-12 | |
| Ideal Recycle Reactor | 7-12 | |
| Examples for Some Simple Reactions | 7-13 | |
| KINETICS OF COMPLEX HOMOGENEOUS REACTIONS | ||
| Chain Reactions | 7-14 | |
| Phosgene Synthesis | 7-14 | |
| Ozone Conversion to Oxygen in Presence of Chlorine | 7-14 | |
| Hydrogen Bromide Synthesis | 7-15 | |
| Chain Polymerization | 7-15 | |
| Nonchain Reactions | 7-15 | |
| Homogeneous Catalysis | 7-15 | |
| Acid-Catalyzed Isomerization of Butene-1 | 7-15 | |
| Enzyme Kinetics | 7-15 | |
| Autocatalysis | 7-16 | |
| INTRINSIC KINETICS FOR FLUID-SOLID CATALYTIC REACTIONS | ||
| Adsorption Equilibrium | 7-16 | |
| Dissociation | 7-17 | |
| Different Sites | 7-17 | |
| Change in Number of Moles | 7-17 | |
| Reactant in the Gas Phase | 7-17 | |
| Chemical Equilibrium in Gas Phase | 7-17 | |
| No Rate-Controlling Step | 7-18 | |
| Liquid-Solid Catalytic Reactions | 7-18 | |
| Biocatalysis | 7-18 | |
| FLUID-SOLID REACTIONS WITH MASS AND HEAT TRANSFER | ||
| Gas-Solid Catalytic Reactions |
