Working Guide to Process Equipment, Third Edition

A distillation tray works efficiently when the vapor and liquid come into intimate contact on the tray deck. To this end, the liquid should flow evenly across the tray deck. The vapor should bubble up evenly through the perforations on the tray deck. The purpose of the outlet weir is to accomplish both these objectives, as follows:
Uneven liquid flow across the tray deck is particularly detrimental to good vapor-liquid mixing. For example, if half of the tray deck has stagnant liquid, then the vapor bubbling through the stagnant liquid cannot alter its composition.
Let me explain. A tray deck is a flat plate with holes. Liquid runs across the plate. Vapor bubbles up through the holes. If liquid only runs across part of this plate, vapor will still bubble up through the holes in the whole plate.
The vapor bubbling up through that portion of the tray deck where the liquid flow is active will mix with the flowing liquid. The flowing liquid will wash out the heavier components from the rising vapors.
On the other hand, the vapor bubbling up through that portion of the tray deck where the liquid flow is zero will also mix with the stagnant liquid. But it s like trying to wash dirty clothes in dirty water. The stagnant liquid cannot wash out the heavier components from the vapors, because it is already saturated with these heavier components.
Uneven liquid flow is promoted by the outlet weir being out of level. Liquid will...