Chemical Engineering License Review, Second Edition

Chapter 9: Psychrometry and Humidification

In dealing with processes involving exchange of mass and energy between a liquid and an essentially insoluble gas, the principles of psychrometry are useful. Important operations to consider are the cooling and humidification and dehumidification of a gas. A familiarity with the use of the psychrometric chart for the air water-vapor system at atmospheric pressure is also essential.

Definitions in Psychrometry

The following is a review of the important definitions used in psychrometry.

Humidity Y Sometimes this is also called specific humidity or humidity ratio. When P is the total pressure which is low enough (near atmospheric) for the gas mixture to be considered ideal, the humidity is given by

where M A

= molecular weight of vapor

M B

= molecular weight of dry gas

p A

= partial pressure of vapor in gas, atm

P

= total pressure, atm

Y

= lb of vapor per lb of vapor-free (dry) gas

Saturation Humidity Y s When p A = P A, the vapor pressure of the liquid at the prevailing temperature, the gas is saturated with the vapor and the saturation humidity is given by

Molal Absolute Humidity Y ? This is defined as the number of moles of vapor per mole of the dry gas or

Thus from Eqs. (9-1) and (9-3),

Percent Relative Humidity or Relative Humidity This is a term which expresses the actual humidity of a gas at a given temperature as a percentage of its saturation humidity...

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