Chemical Engineering License Review, Second Edition

Chapter 3: Heat Transfer

There are three modes of heat transfer: conduction, convection, and radiation. The basic laws governing these are covered in this chapter.

Thermal Conduction

Fourier's law states that

where q k

= heat transferred by conduction, Btu/h

k

= thermal conductivity of material, Btu/(h ft 2 F/ft)

A

= area of cross section perpendicular to direction of heat flow, ft 2

dT/ dx

= temperature gradient in the direction of heat flow, F/ft

If k is independent of temperature,

where L is the distance between the hot and cold surfaces in the direction of heat flow, in feet.

Thermal Radiation

By the Stefan-Boltzmann law, the heat transfer by radiation for a blackbody is

where q r

= heat transfer by radiation, Btu/h

?

= Stefan-Boltzmann constant

= 0.173 10 ?8 Btu/h ft 2 R 4

= 5.67 10 ?8 W/m 2 K 4

A 1

= area of radiating surface, ft 2

T 1

= radiating surface temperature, R

Real bodies emit radiation at lower rates than blackbodies. Gray bodies emit a constant fraction of the blackbody emission at each wavelength at a given temperature. The net rate of the radiation heat transfer from a gray body at T 1 to a surrounding blackbody at T 2 is given by

where ? 1 is the emissivity of the gray surface.

Heat transfer between two gray bodies is given...

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