Biotreatment of Industrial Effluents

Chapter 30: Gaseous Pollutants and Volatile Organics

Sulfur dioxide, nitrogen oxides, volatile organic compounds (VOCs), and particulates are the four major components of air pollution and are the main causes of environmental damage and many diseases, including cancer. The sulfur and nitrogen oxides and particulates are the result of burning petroleum fuels, coal, wood, etc. Printing and coating facilities and foundries, as well as the electronics, petrochemical, metal finishing, and paint industries, produce VOCs, which include solvent thinners, degreasers, cleaners, lubricants, and liquid fuels. They originate from breathing and loading losses from storage tanks, venting of process vessels, and leaks from piping and equipment, wastewater streams, and heat exchange systems. A few common VOCs are methane, ethane, tetrachloroethane, methyl chloride, and various chlorohydrocarbons, perfluorocarbons, styrene, and naphthalenes. The European Community emissions limit is 35 g total organic compounds (TOC) per cubic meter of gasoline loaded (35 g TOC/m 3): the U.S. Environmental Protection Agency emission limit is 10 g TOC/m 3. Particulates from air can be removed using several well established physical methods that use a gravity settler, centrifugal collector, wet spray venturi collector, electrostatic precipitator, and fabric filter.

Physical Methods

Two general methods for abatement include recovery and destruction (see Fig. 30-1). The former method leads to reuse of the chemical and hence has a cost benefit. The latter method includes converting the chemical to a harmless product or into a liquid or solid pollutant that can be treated with another well established technology. Chemical, thermal, and biochemical approaches could be followed for destroying...

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