Epoxy Adhesive Formulations

Chapter 12: Elevated-Temperature Curing Liquid and Paste Epoxy Adhesives

12.1 INTRODUCTION

Although room temperature curing epoxy adhesives are very convenient to use in many applications, the short working life, long curing time, and inherently suboptimal physical properties of these systems are often a serious disadvantage to their use. In these cases, elevated-temperature curing epoxy adhesives are required. The major advantages and disadvantages of elevated-temperature curing epoxy adhesives are shown in Table 12.1.

Table 12.1: Advantages and Disadvantages of Elevated-Temperature Curing Epoxy Adhesives

Advantages

Disadvantages

Fast cure time results in higher production speed and less tie-up of fixturing equipment

Greater internal stresses than in room temperature curing adhesive because of

  • Higher shrinkage on polymerization

  • Thermal expansion coefficient differences

Long working life

More brittle than room temperature curing adhesives (poorer peel and impact properties)

High-temperature resistance

Safety and hazardous nature of high temperatures

Good chemical resistance

One-component systems have shorter shelf life; may require refrigeration

One-component systems possible (no need to meter and mix)

Solid systems easier to apply, less of a health hazard than liquids or pastes

Long shelf life for two-component systems

Energy consumption

Solid systems (film, preforms, powders) possible

Viscosity of adhesive decrease at elevated temperature could result in starved joint

Viscosity decrease at elevated temperature provides more efficient wetting of substrate

Heat curing epoxy systems may consist of one or two components. The nomenclature is similar to that employed with the room temperature curing adhesives (e.g., resin component, curing agent component, 2K system, etc.). Many heat curing epoxy adhesives systems are liquids or pastes. However,...

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