Optical System Design

IR Materials

While there are many glass types available for visible systems, there are only a very limited number of materials that can be effectively used in the MWIR and LWIR spectral bands. Table 12.1 shows the more common materials and their most important properties. Figure 12.13 shows a plot of the transmittance of the more common IR transmitting materials. It is important to note that these data include surface reflection losses, and often a significantly higher transmittance results after applying high-efficiency antireflection coatings.

Table 12.1: Properties of Common Optical Materials in the Thermal Infrared
Material Refractive Index at 4 m Refractive Index at 10 m dn / dt / C ) Comments

Germanium

4.0243

4.0032

0.000396

Expensive, large dn/ dt

Silicon

3.4255

3.4179 [*]

0.000150

Large dn/ dt

Zinc sulfide, CVD

2.2520

2.2005

0.0000433

Zinc selenide, CVD

2.4331

2.4065

0.000060

Expensive, very low absorption

AMTIR I (Ge/As/SE:33/12/55)

2.5141

2.4976

0.000072

Magnesium fluoride

1.3526

[ ]

0.000020

Low cost, no ctg required

Sapphire

1.6753

[ ]

0.000010

Very hard, low emissivity at high temperature

Arsenic trisulfide

2.4112

2.3816

[ ]

Calcium fluoride

1.4097

[ ]

0.000011

Barium fluoride

1.4580

[ ]

?0.000016

[*]Not recommended.

[ ]Does not transmit.

[ ]Not available.

[ ]Transmits up to 10 m but drops abruptly.


Figure 12.13: Spectral Transmittance of ir Materials, Including Surface Losses

Figure 12.14 shows a "glass" map where we plot the refractive index in the ordinate versus the V# in the...

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