OrganoMetallics Inorganic Chemicals and Compounds
Last Updated: April 1, 2025
Description
OrganoMetallics are a class of inorganic compounds characterized by the presence of carbon atoms directly bonded to a metal ion. These compounds are integral in various chemical processes due to their unique structural properties.
Working Principle
OrganoMetallic compounds function through the interaction of metal ions with carbon atoms, forming stable bonds that facilitate various chemical reactions. This bonding is crucial because it allows for the manipulation of the electronic properties of the metal, making these compounds highly useful in catalysis and other chemical transformations. The ability to alter the reactivity of the metal center through the organic ligands makes OrganoMetallics versatile and valuable in chemical synthesis.
Applications
OrganoMetallic compounds are widely used in catalysis, particularly in the polymerization of olefins, which is essential in the production of plastics. They also play a critical role in the synthesis of fine chemicals and pharmaceuticals, where precise control over chemical reactions is required. Additionally, OrganoMetallics are employed in the development of new materials with specific electronic properties, such as conductive polymers and advanced coatings.
Advantages over other Inorganic Chemicals and Compounds
One of the primary advantages of OrganoMetallics over other inorganic compounds is their ability to act as catalysts in a wide range of chemical reactions, which can significantly enhance reaction rates and selectivity. This catalytic efficiency often leads to lower energy consumption and reduced waste production in industrial processes. Furthermore, the versatility of OrganoMetallics in modifying the electronic properties of metals allows for the development of specialized materials that are not achievable with other inorganic compounds.
Limitations
Despite their advantages, OrganoMetallic compounds can be sensitive to air and moisture, which can limit their stability and handling. This sensitivity often necessitates the use of inert atmospheres and specialized equipment, increasing the complexity and cost of their use. Additionally, some OrganoMetallics can be toxic or environmentally hazardous, requiring careful management and disposal.
Considerations
When considering the use of OrganoMetallic compounds, it is important to account for the initial costs associated with their synthesis and the specialized equipment needed for their handling. Operating expenses can also be higher due to the need for controlled environments to maintain stability. However, the durability and effectiveness of OrganoMetallics in catalysis can offset these costs by improving process efficiencies. Replacement and maintenance costs should also be considered, particularly in applications where the compounds may degrade or become contaminated over time.
from Rieke Metals, Inc.
3-Methoxyphenylmagnesium bromide. Formula. C. 7H7BrMgO. mol weight. 211.35 [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H7BrMgO
- Chemical Name: 3-Methoxyphenylmagnesium Bromide
- CAS Number: 36282-40-3
from Gelest, Inc.
Application. Can be cross-coupled with aryl chlorides.1 Used to acylate aryl triflates.2 Undergoes Stille cross-coupling reactions as employed in the syntheses of three cladiellins.3 Cross-couples with vinyl sulfides.4 Can be cross-coupled with heteroaromatic chlorides.5. Reference. 1. Soderquist,... [See More]
- Type: OrganoMetallics
- CAS Number: 97674-02-7
- Chemical Formula: C 1 6 H 3 4 OSn
- Flash Point: 235
from Rieke Metals, Inc.
4-Methoxyphenylmagnesium bromide. Formula. C. 7H7BrMgO. mol weight. 211.35 [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H7BrMgO
- Chemical Name: 4-Methoxyphenylmagnesium Bromide
- CAS Number: 13139-86-1
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 1: no significant reaction with aqueous systems. Application. Reviewed.1 Conjugatively allylates alkylidene Meldrum ’s acids.10 Generates homoallylic amines with aldehydes and amines.11 Allylates bromides and chloroethers.,2,3 Radical initiation... [See More]
- Type: OrganoMetallics
- CAS Number: 24850-33-7
- Chemical Formula: C 1 5 H 3 2 Sn
- Flash Point: 217
from Rieke Metals, Inc.
2-Methoxyphenylmagnesium bromide. Formula. C. 7H7BrMgO. mol weight. 211.35 [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H7BrMgO
- Chemical Name: 2-Methoxyphenylmagnesium Bromide
- CAS Number: 16750-63-3
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 1: no significant reaction with aqueous systems. Application. Employed in preparation of allyl lithium.1,2 Conjugatively allylates alkylidene Meldrum ’s acids.3. Fieser. F &F: Vol. 13, p 14; Vol. 14, p 20. Reference. 1. Yamamoto, Y. et al. J. [See More]
- Type: OrganoMetallics
- CAS Number: 76-63-1
- Chemical Formula: C 2 1 H 2 0 Sn
from Rieke Metals, Inc.
3-Chlorophenylmagnesium bromide. Formula. C. 6H4BrClMg. mol weight. 215.77. CAS. 36229-42-2. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H4BrClMg
- Chemical Name: 3-Chlorophenylmagnesium Bromide
- CAS Number: 36229-42-2
from Gelest, Inc.
Safety. Packaging Under None [See More]
- Type: OrganoMetallics
- CAS Number: 1302-74-5
from Rieke Metals, Inc.
3,4-Difluorophenylmagnesium bromide. Formula. C. 6H3BrF2Mg. mol weight. 217.3. CAS. 90897-92-0. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H3BrF2Mg
- Chemical Name: 3,4-Difluorophenylmagnesium Bromide
- CAS Number: 90897-92-0
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 0: forms stable aqueous solutions. Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 16919-19-0
- Chemical Formula: H 8 F 6 N 2 Si
from Rieke Metals, Inc.
3,5-Difluorophenylmagnesium bromide. Formula. C. 6H3BrF2Mg. mol weight. 217.3. CAS. 62351-47-7. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H3BrF2Mg
- Chemical Name: 3,5-Difluorophenylmagnesium Bromide
- CAS Number: 62351-47-7
from Gelest, Inc.
Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- Chemical Formula: C 3 2 H 4 8 Sn
from Rieke Metals, Inc.
4-N,N-Dimethylanilinemagnesium bromide. Formula. C. 8H10BrMgN. mol weight. 224.39. CAS. 7353-91-5. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C8H10BrMgN
- Chemical Name: 4-N,N-Dimethylanilinemagnesium Bromide
- CAS Number: 7353-91-5
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Application. Catalyst for the formation of carbamates from isocyanates and alcohols.1 Employed in formation of SnOx coating by MOCVD.2 Forms conductive indium-tin oxide films.3. Reference. 1. Francis, T. et al. F... [See More]
- Type: OrganoMetallics
- CAS Number: 301-10-0
- Chemical Formula: C 1 6 H 3 0 O 4 Sn
- Flash Point: 230
from Rieke Metals, Inc.
(1,3-Dioxan-2-ylethyl )magnesium bromide. Formula. C. 6H11BrMgO2. mol weight. 219.37. CAS. 480438-44-6. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H11BrMgO2
- Chemical Name: (1,3-Dioxan-2-ylethyl )Magnesium Bromide
- CAS Number: 480438-44-6
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 49556-16-3
- Chemical Formula: C 2 0 H 3 8 O 4 Sn
from Rieke Metals, Inc.
3-Fluorophenylmagnesium bromide. Formula. C. 6H4BrFMg. mol weight. 199.31. CAS. 17318-03-5. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H4BrFMg
- Chemical Name: 3-Fluorophenylmagnesium Bromide
- CAS Number: 17318-03-5
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 5: forms reversible hydrate. Surface Tension (mN/m) 30.6. Application. Converts amines to dithiocarbamates.1 Mild oxidizing agent in combination with bromine.2. Fieser. F &F: Vol. 6, p 56; Vol. 7, p 26; Vol. 8, p 43; Vol. 9, p. 53; Vol. 11, p. 62;... [See More]
- Type: OrganoMetallics
- CAS Number: 56-35-9
- Chemical Formula: C 2 4 H 5 4 OSn 2
- Flash Point: 334
from Rieke Metals, Inc.
1-Naphthylmagnesium bromide. Formula. C. 10H7BrMg. mol weight. 231.38. CAS. 703-55-9. Notes. 0.25 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C10H7BrMg
- Chemical Name: 1-Naphthylmagnesium Bromide
- CAS Number: 703-55-9
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 4: no reaction with water under neutral conditions. Application. Reviewed.1 Boron trichloride complex reviewed.2 Sulfuration reagent - converts ketones to thiocarbonyls3, 1,4-diketones to thiophenes.4. Reference. 1. Steliou, K. e-EROS, 2001. 2. [See More]
- Type: OrganoMetallics
- CAS Number: 4808-30-4
- Chemical Formula: C 2 4 H 5 4 SSn 2
from Rieke Metals, Inc.
9-Phenanthrylmagnesium bromide. Formula. C. 14H9BrMg. mol weight. 281.44. CAS. 71112-64-6. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C14H9BrMg
- Chemical Name: 9-Phenanthrylmagnesium Bromide
- CAS Number: 71112-64-6
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Safety. Packaging Under Nitrogen. ALD Material. Atomic layer deposition (ALD) is a chemically self-limiting deposition technique that is based on the sequential use of a gaseous chemical process. A thin film (as fine... [See More]
- Type: OrganoMetallics
- CAS Number: 4551-16-0
- Chemical Formula: C 6 H 1 8 Si 2 Te
from Rieke Metals, Inc.
4-Phenoxyphenylmagnesium bromide. Formula. C. 12H9BrMgO. mol weight. 273.42. CAS. 21473-02-9. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C12H9BrMgO
- Chemical Name: 4-Phenoxyphenylmagnesium Bromide
- CAS Number: 21473-02-9
![BIS[BIS(TRIMETHYLSILYL)AMINO]GERMANIUM(II) -- GEB1025 - Image](https://partimages.globalspec.com/16/3616/8313616_medium.png "BIS[BIS(TRIMETHYLSILYL)AMINO]GERMANIUM(II) -- GEB1025 - Image")
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents. Application. Intermediate for germazene.1 Forms poly(germanium enolates) by reaction with ?,?-unsaturated ketones.2 Reacts with carbon dioxide to form silylated isocyanates and carbodiimides.3... [See More]
- Type: OrganoMetallics
- CAS Number: 55290-25-0
- Chemical Formula: C 1 2 H 3 6 GeN 2 Si 4
from Rieke Metals, Inc.
4-Thioanisolemagnesium bromide. Formula. C. 7H7BrMgS. mol weight. 227.41. CAS. 18620-04-7. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H7BrMgS
- Chemical Name: 4-Thioanisolemagnesium Bromide
- CAS Number: 18620-04-7
![BIS[BIS(TRIMETHYLSILYL)AMINO]TIN(II), 95% -- SNB1025 - Image](https://partimages.globalspec.com/21/3771/8313771_medium.png "BIS[BIS(TRIMETHYLSILYL)AMINO]TIN(II), 95% -- SNB1025 - Image")
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents. Application. Promotes conversion of aldehydes and ketones to N,N-dialkyleneamines.1,2. Reference. 1. Burnell-Curty, C. et al. J. Org. Chem. 1992, 57, 5063. 2. Burnell-Curty, C. et al. Synlett 1993,... [See More]
- Type: OrganoMetallics
- CAS Number: 59863-13-7
- Chemical Formula: C 1 2 H 3 6 N 2 Si 4 Sn
- Flash Point: 133
from Rieke Metals, Inc.
4-n-Butylphenylmagnesium bromide. Formula. C. 10H13BrMg. mol weight. 237.43. CAS. 185416-14-2. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C10H13BrMg
- Chemical Name: 4-n-Butylphenylmagnesium Bromide
- CAS Number: 185416-14-2
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 15961-23-6
- Chemical Formula: C 3 H 5 Cl 3 GeO 2
from Rieke Metals, Inc.
4-tert-Butylphenylmagnesium bromide. Formula. C. 10H13BrMg. mol weight. 237.43. CAS. 63488-10-8. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C10H13BrMg
- Chemical Name: 4-Tert-Butylphenylmagnesium Bromide
- CAS Number: 63488-10-8
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 4: no reaction with water under neutral conditions. Application. Catalyst in silicone RTV cures.1,2 Used in preparation of transparent electrically conductive films.3. Reference. 1. Lockhardt, T. et al. U.S. Patent 4,517,337, 1985. 2. Wengrovius, J. U.S. [See More]
- Type: OrganoMetallics
- CAS Number: 22673-19-4
- Chemical Formula: C 1 8 H 3 2 O 4 Sn
- Flash Point: 196
from Rieke Metals, Inc.
4-n-Propylphenylmagnesium bromide. Formula. C. 9H11BrMg. mol weight. 223.4. CAS. 87942-08-3. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C9H11BrMg
- Chemical Name: 4-n-Propylphenylmagnesium Bromide
- CAS Number: 87942-08-3
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 4: no reaction with water under neutral conditions. Application. Charge control agent for toner powder.1. Reference. 1. Shindo, S. et al. Chem. Abstr. 113, 241462j; Jpn. Patent 01,310,360, 1989. Safety. Hazard Info oral rat, LD50: 136 mg/kg. Packaging... [See More]
- Type: OrganoMetallics
- CAS Number: 2781-10-4
- Chemical Formula: C 2 4 H 4 8 O 4 Sn
- Purity: 95
from Rieke Metals, Inc.
4-Ethylphenylmagnesium bromide. Formula. C. 8H9BrMg. mol weight. 209.38. CAS. 22873-28-5. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C8H9BrMg
- Chemical Name: 4-Ethylphenylmagnesium Bromide
- CAS Number: 22873-28-5
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 2: reacts with aqueous acid. Safety. Hazard Info oral rat, LD50: 1,690 mg/kg. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 25168-21-2
- Chemical Formula: C 3 2 H 5 6 O 8 Sn
- Flash Point: 253
from Rieke Metals, Inc.
5-Fluoro-2-methylphenylmagnesium bromide. Formula. C. 7H6BrFMg. mol weight. 213.34. CAS. 186496-59-3. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H6BrFMg
- Chemical Name: 5-Fluoro-2-Methylphenylmagnesium Bromide
- CAS Number: 186496-59-3
from Gelest, Inc.
Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 1185-81-5
- Chemical Formula: C 3 2 H 6 8 S 2 Sn
- Flash Point: 399
from Rieke Metals, Inc.
4-Fluoro-2-methylphenylmagnesium bromide. Formula. C. 7H6BrFMg. mol weight. 213.34. CAS. 30897-90-6. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H6BrFMg
- Chemical Name: 4-Fluoro-2-Methylphenylmagnesium Bromide
- CAS Number: 30897-90-6
from Gelest, Inc.
Application. Catalyst for two-component condensation cure silicone RTVs.1. Reference. 1. Chadho, R. et al. U.S. Patent 3,574,785, 1971. Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 14254-22-9
- Chemical Formula: C 1 2 H 2 7 ClOSn
- Purity: 95
from Rieke Metals, Inc.
3-Fluoro-4-methylphenylmagnesium bromide. Formula. C. 7H6BrFMg. mol weight. 213.34. CAS. 185077-02-5. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H6BrFMg
- Chemical Name: 3-Fluoro-4-Methylphenylmagnesium Bromide
- CAS Number: 185077-02-5
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Safety. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 3349-36-8
- Chemical Formula: C 1 6 H 3 6 O 2 Sn
- Flash Point: 241
from Rieke Metals, Inc.
3,4,5-Trifluorophenylmagnesium bromide. Formula. C. 6H2BrF3Mg. mol weight. 235.29. CAS. 156006-28-9. Notes. 0.5 M in Tetrahydrofuran [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H2BrF3Mg
- Chemical Name: 3,4,5-Trifluorophenylmagnesium Bromide
- CAS Number: 156006-28-9
from Gelest, Inc.
Safety. Hazard Info oral mus, LD50: 109.7 mg/kg. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 1067-33-0
- Chemical Formula: C 1 2 H 2 4 O 4 Sn
- Flash Point: 289
from Rieke Metals, Inc.
3,4-Dichlorobenzylmagnesium chloride. Formula. C. 7H5Cl3Mg. mol weight. 219.79. CAS. 61259-69-6. Notes. 0.25 M in Diethyl Ether [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H5Cl3Mg
- Chemical Name: 3,4-Dichlorobenzylmagnesium Chloride
- CAS Number: 61259-69-6
from Gelest, Inc.
Application. Catalyzes condensations of cyclic ketones with amines to form imines.1 Blocking agent for diols.2 Effective phase transfer catalyst.3 Forms high M.W. polystannanes by Wurtz coupling.4 Catalyzes phenylsilane reductive aminations of aldehydes and ketones.5. Reference. 1. Stetin, C. et al. [See More]
- Type: OrganoMetallics
- CAS Number: 683-18-1
- Chemical Formula: C 8 H 1 8 Cl 2 Sn
- Flash Point: 334
from Rieke Metals, Inc.
3,5-Dichlorobenzylmagnesium chloride. Formula. C. 7H5Cl3Mg. mol weight. 219.79. CAS. 107549-25-7. Notes. 0.25 M in Diethyl Ether [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H5Cl3Mg
- Chemical Name: 3,5-Dichlorobenzylmagnesium Chloride
- CAS Number: 107549-25-7
from Gelest, Inc.
Safety. Hazard Info oral rat, LD50: 175-1,600mg/kg. Packaging Under Nitrogen [See More]
- Type: OrganoMetallics
- CAS Number: 77-58-7
- Chemical Formula: C 3 2 H 6 4 O 4 Sn
- Flash Point: 448
from Rieke Metals, Inc.
4-Chlorobenzylmagnesium chloride. Formula. C. 7H6Cl2Mg. mol weight. 185.34. CAS. 874-72-6. Notes. 0.25 M in Diethyl Ether [See More]
- Type: OrganoMetallics
- Chemical Formula: C7H6Cl2Mg
- Chemical Name: 4-Chlorobenzylmagnesium Chloride
- CAS Number: 874-72-6
from Gelest, Inc.
Additional Properties. Hydrolytic Sensitivity 7: reacts slowly with moisture/water. Application. Yields dialkylcarbonates on reaction with ethylene carbonate.1 Couples thioacetates to disulfides.2. Reference. 1. Sakai, S. et al. J. Chem. Soc., Chem. Commun. 1975, 265. 2. Sato, T. et al. Tetrahedron... [See More]
- Type: OrganoMetallics
- CAS Number: 1067-55-6
- Chemical Formula: C 1 0 H 2 4 O 2 Sn
- Flash Point: 230
from Rieke Metals, Inc.
2-tert-Butoxy-2-oxoethylzinc chloride. !ORGANOZINC REAGENTS ARE NOW AVAILABLE ON COMMERCIAL SCALE!. Please contact us at sales@riekemetals.com for ordering and bulk pricing. Our products are available in an electronic database in either .db or .sd formats. If you need a Halide converted into an... [See More]
- Type: OrganoMetallics
- Chemical Formula: C6H11ClO2Zn
- Chemical Name: 2-tert-butoxy-2-oxoethylzinc Chloride
- CAS Number: 321745-86-2
from Gelest, Inc.
Application. Employed in selective oxidation of alcohols.1 Deacetylates N- and O- acetyl nucleosides.2. Reference. 1. David, S. et al. J. Chem. Soc., Perkin Trans. 1979, 1, 1568. 2. Chwang, T. et al. J. Carb. Nucleosides Nucleotides 1980, 7, 159. Safety. Hazard Info oral rat, LD50: 487-520 mg/kg. [See More]
- Type: OrganoMetallics
- CAS Number: 818-08-6
- Chemical Formula: (C 8 H 1 8 OSn)n